TY - JOUR
T1 - Preparation of coal slurry with organic solvents
AU - Shin, Yu Jen
AU - Shen, Yun Hwei
N1 - Funding Information:
The authors are grateful to The National Science Council of R.O.C. for funding this study.
Copyright:
Copyright 2020 Elsevier B.V., All rights reserved.
PY - 2007/6
Y1 - 2007/6
N2 - In this study, various organic solvents were used to prepare coal slurries and the rheological and thermal properties of coal-organic solvent slurries were examined. Solvents with molecules containing unpaired electrons (high basicity) show high extraction power and cause swelling of coal. Therefore, coal-organic solvent slurries usually showed higher viscosities compared to coal-water slurry. In addition, coal slurries prepared by alcohols and cyclohexanone demonstrated lower settling rates but a high specific sedimentation volume presumably because these solvents swelled coal particles well and led to the formation of weak gel structures in the bulk. In addition, ethanol and cyclohexanone are capable of breaking a considerable amount of hydrogen bonds in coal and subsequently opening up the structures. Thus, more surface area is available for combustion and the combustion rate of coal slurries was increased.
AB - In this study, various organic solvents were used to prepare coal slurries and the rheological and thermal properties of coal-organic solvent slurries were examined. Solvents with molecules containing unpaired electrons (high basicity) show high extraction power and cause swelling of coal. Therefore, coal-organic solvent slurries usually showed higher viscosities compared to coal-water slurry. In addition, coal slurries prepared by alcohols and cyclohexanone demonstrated lower settling rates but a high specific sedimentation volume presumably because these solvents swelled coal particles well and led to the formation of weak gel structures in the bulk. In addition, ethanol and cyclohexanone are capable of breaking a considerable amount of hydrogen bonds in coal and subsequently opening up the structures. Thus, more surface area is available for combustion and the combustion rate of coal slurries was increased.
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U2 - 10.1016/j.chemosphere.2006.12.049
DO - 10.1016/j.chemosphere.2006.12.049
M3 - Article
C2 - 17276487
AN - SCOPUS:34047147512
SN - 0045-6535
VL - 68
SP - 389
EP - 393
JO - Chemosphere
JF - Chemosphere
IS - 2
ER -