Preparation of platinum nanoparticles in salt-induced micelles of dumbbell-shaped ABA copolymer

Wuu Jyh Liang, Chia Hui Lien, Ping-Lin Kuo

Research output: Contribution to journalArticle

12 Citations (Scopus)

Abstract

The interaction of a water-soluble ABA type of dumbbell-shaped polyethyleniminated copolymers (D400(EI)8) with H 2PtCl6 in aqueous medium is studied by means of UV-visible absorption spectra, dynamic light scattering (DLS) measurements, and transmission electron microscopy (TEM). From TEM images of the stained polymer, it is evident that the spherical and well-structured polymer micelles are formed by the introduction of H2PtCl6, and totally nonstructured micelles are formed from D400(EI)8 itself. These findings coincide with the results obtained from DLS measurements, where the narrowly distributed polymer aggregates are remarkably observed. Moreover, it is directly evidenced from TEM that the reduced Pt(0) nanoparticles are embedded in the polyethylenimine (PEI) block at the exterior of micelles, whereas the polyoxypropylene (PPO) block is surrounded by the PEI block. Additionally, the resulting Pt(0) colloids are very stable for at least 4 months.

Original languageEnglish
Pages (from-to)371-375
Number of pages5
JournalJournal of Colloid And Interface Science
Volume294
Issue number2
DOIs
Publication statusPublished - 2006 Feb 15

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Micelles
Platinum
Polyethyleneimine
Polymers
Copolymers
Salts
Dynamic light scattering
Nanoparticles
Transmission electron microscopy
Polyphenylene oxides
Colloids
Absorption spectra
Water

All Science Journal Classification (ASJC) codes

  • Electronic, Optical and Magnetic Materials
  • Biomaterials
  • Surfaces, Coatings and Films
  • Colloid and Surface Chemistry

Cite this

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abstract = "The interaction of a water-soluble ABA type of dumbbell-shaped polyethyleniminated copolymers (D400(EI)8) with H 2PtCl6 in aqueous medium is studied by means of UV-visible absorption spectra, dynamic light scattering (DLS) measurements, and transmission electron microscopy (TEM). From TEM images of the stained polymer, it is evident that the spherical and well-structured polymer micelles are formed by the introduction of H2PtCl6, and totally nonstructured micelles are formed from D400(EI)8 itself. These findings coincide with the results obtained from DLS measurements, where the narrowly distributed polymer aggregates are remarkably observed. Moreover, it is directly evidenced from TEM that the reduced Pt(0) nanoparticles are embedded in the polyethylenimine (PEI) block at the exterior of micelles, whereas the polyoxypropylene (PPO) block is surrounded by the PEI block. Additionally, the resulting Pt(0) colloids are very stable for at least 4 months.",
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Preparation of platinum nanoparticles in salt-induced micelles of dumbbell-shaped ABA copolymer. / Liang, Wuu Jyh; Lien, Chia Hui; Kuo, Ping-Lin.

In: Journal of Colloid And Interface Science, Vol. 294, No. 2, 15.02.2006, p. 371-375.

Research output: Contribution to journalArticle

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AB - The interaction of a water-soluble ABA type of dumbbell-shaped polyethyleniminated copolymers (D400(EI)8) with H 2PtCl6 in aqueous medium is studied by means of UV-visible absorption spectra, dynamic light scattering (DLS) measurements, and transmission electron microscopy (TEM). From TEM images of the stained polymer, it is evident that the spherical and well-structured polymer micelles are formed by the introduction of H2PtCl6, and totally nonstructured micelles are formed from D400(EI)8 itself. These findings coincide with the results obtained from DLS measurements, where the narrowly distributed polymer aggregates are remarkably observed. Moreover, it is directly evidenced from TEM that the reduced Pt(0) nanoparticles are embedded in the polyethylenimine (PEI) block at the exterior of micelles, whereas the polyoxypropylene (PPO) block is surrounded by the PEI block. Additionally, the resulting Pt(0) colloids are very stable for at least 4 months.

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