Quantum valence criticality in a correlated metal

Kentaro Kuga, Yosuke Matsumoto, Mario Okawa, Shintaro Suzuki, Takahiro Tomita, Keita Sone, Yasuyuki Shimura, Toshiro Sakakibara, Daisuke Nishio-Hamane, Yoshitomo Karaki, Yasutaka Takata, Masaharu Matsunami, Ritsuko Eguchi, Munetaka Taguchi, Ashish Atma Chainani, Shik Shin, Kenji Tamasaku, Yoshinori Nishino, Makina Yabashi, Tetsuya IshikawaSatoru Nakatsuji

Research output: Contribution to journalArticle

4 Citations (Scopus)

Abstract

A valence critical end point existing near the absolute zero provides a unique case for the study of a quantum version of the strong density fluctuation at the Widom line in the supercritical fluids. Although singular charge and orbital dynamics are suggested theoretically to alter the electronic structure significantly, breaking down the standard quasi-particle picture, this has never been confirmed experimentally to date. We provide the first empirical evidence that the proximity to quantum valence criticality leads to a clear breakdown of Fermi liquid behavior. Our detailed study of the mixed valence compound a-YbAlB4 reveals that a small chemical substitution induces a sharp valence crossover, accompanied by a pronounced non-Fermi liquid behavior characterized by a divergent effective mass and unusual T/B scaling in the magnetization.

Original languageEnglish
Article numbereaao3547
JournalScience Advances
Volume4
Issue number2
DOIs
Publication statusPublished - 2018 Feb 23

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Metals

All Science Journal Classification (ASJC) codes

  • General

Cite this

Kuga, K., Matsumoto, Y., Okawa, M., Suzuki, S., Tomita, T., Sone, K., ... Nakatsuji, S. (2018). Quantum valence criticality in a correlated metal. Science Advances, 4(2), [eaao3547]. https://doi.org/10.1126/sciadv.aao3547
Kuga, Kentaro ; Matsumoto, Yosuke ; Okawa, Mario ; Suzuki, Shintaro ; Tomita, Takahiro ; Sone, Keita ; Shimura, Yasuyuki ; Sakakibara, Toshiro ; Nishio-Hamane, Daisuke ; Karaki, Yoshitomo ; Takata, Yasutaka ; Matsunami, Masaharu ; Eguchi, Ritsuko ; Taguchi, Munetaka ; Chainani, Ashish Atma ; Shin, Shik ; Tamasaku, Kenji ; Nishino, Yoshinori ; Yabashi, Makina ; Ishikawa, Tetsuya ; Nakatsuji, Satoru. / Quantum valence criticality in a correlated metal. In: Science Advances. 2018 ; Vol. 4, No. 2.
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Kuga, K, Matsumoto, Y, Okawa, M, Suzuki, S, Tomita, T, Sone, K, Shimura, Y, Sakakibara, T, Nishio-Hamane, D, Karaki, Y, Takata, Y, Matsunami, M, Eguchi, R, Taguchi, M, Chainani, AA, Shin, S, Tamasaku, K, Nishino, Y, Yabashi, M, Ishikawa, T & Nakatsuji, S 2018, 'Quantum valence criticality in a correlated metal', Science Advances, vol. 4, no. 2, eaao3547. https://doi.org/10.1126/sciadv.aao3547

Quantum valence criticality in a correlated metal. / Kuga, Kentaro; Matsumoto, Yosuke; Okawa, Mario; Suzuki, Shintaro; Tomita, Takahiro; Sone, Keita; Shimura, Yasuyuki; Sakakibara, Toshiro; Nishio-Hamane, Daisuke; Karaki, Yoshitomo; Takata, Yasutaka; Matsunami, Masaharu; Eguchi, Ritsuko; Taguchi, Munetaka; Chainani, Ashish Atma; Shin, Shik; Tamasaku, Kenji; Nishino, Yoshinori; Yabashi, Makina; Ishikawa, Tetsuya; Nakatsuji, Satoru.

In: Science Advances, Vol. 4, No. 2, eaao3547, 23.02.2018.

Research output: Contribution to journalArticle

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T1 - Quantum valence criticality in a correlated metal

AU - Kuga, Kentaro

AU - Matsumoto, Yosuke

AU - Okawa, Mario

AU - Suzuki, Shintaro

AU - Tomita, Takahiro

AU - Sone, Keita

AU - Shimura, Yasuyuki

AU - Sakakibara, Toshiro

AU - Nishio-Hamane, Daisuke

AU - Karaki, Yoshitomo

AU - Takata, Yasutaka

AU - Matsunami, Masaharu

AU - Eguchi, Ritsuko

AU - Taguchi, Munetaka

AU - Chainani, Ashish Atma

AU - Shin, Shik

AU - Tamasaku, Kenji

AU - Nishino, Yoshinori

AU - Yabashi, Makina

AU - Ishikawa, Tetsuya

AU - Nakatsuji, Satoru

PY - 2018/2/23

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AB - A valence critical end point existing near the absolute zero provides a unique case for the study of a quantum version of the strong density fluctuation at the Widom line in the supercritical fluids. Although singular charge and orbital dynamics are suggested theoretically to alter the electronic structure significantly, breaking down the standard quasi-particle picture, this has never been confirmed experimentally to date. We provide the first empirical evidence that the proximity to quantum valence criticality leads to a clear breakdown of Fermi liquid behavior. Our detailed study of the mixed valence compound a-YbAlB4 reveals that a small chemical substitution induces a sharp valence crossover, accompanied by a pronounced non-Fermi liquid behavior characterized by a divergent effective mass and unusual T/B scaling in the magnetization.

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Kuga K, Matsumoto Y, Okawa M, Suzuki S, Tomita T, Sone K et al. Quantum valence criticality in a correlated metal. Science Advances. 2018 Feb 23;4(2). eaao3547. https://doi.org/10.1126/sciadv.aao3547