Recent advancement in deoxygenation of fatty acids via homogeneous catalysis for biofuel production

Mojtaba Tabandeh, Chin Kui Cheng, Gabriele Centi, Pau Loke Show, Wei Hsin Chen, Tau Chuan Ling, Hwai Chyuan Ong, Eng Poh Ng, Joon Ching Juan, Su Shiung Lam

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1 Citation (Scopus)


Fuel-like hydrocarbons (also known as biofuel) isolated from the deoxygenation of fatty acids present different advantages as compared with fossil fuels. In particular, the homogeneous and heterogeneous catalytic deoxygenation methods have been the center of attention during recent years. Although catalytic deoxygenation of fatty acids via heterogeneous catalysis has been widely investigated, there is a high demand to review the progress in using the homogeneous catalysis pathways. Among the various homogeneous pathways, radical-based reactions and transition metal catalysis demonstrate the most promising results in the decarboxylation and decarbonylation processes. It is shown that radical-based reactions are more active in decarboxylation meanwhile the transition metal catalysts are rather selective to decarbonylation of fatty acids. Besides, the reaction conditions and type of catalysts are capable of enhancing biofuel production. Homogenous catalysis provides the huge potential for commercializing viability of biofuel via deoxygenation of fatty acids.

Original languageEnglish
Article number111207
JournalMolecular Catalysis
Publication statusAccepted/In press - 2020

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Process Chemistry and Technology
  • Physical and Theoretical Chemistry


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