Schottky barrier mediated single-polarity resistive switching in Pt layer-included TiOx memory device

Yu Lung Chung, Pei Ying Lai, Ying Chiuan Chen, Jen Sue Chen

Research output: Contribution to journalArticle

15 Citations (Scopus)


A distinct unipolar but single-polarity resistive switching behavior is observed in a TiOx/Pt/TiOx trilayer structure, formed by thermal oxidation of a Ti/Pt/Ti stack. As a comparison, a memory device with a single TiOx active layer (without addition of Pt midlayer) is also fabricated but it cannot perform resistive switching. Energy band diagrams are illustrated to realize the modulation of Schottky barrier junctions and current conduction in TiOx-based devices under various biasing polarities. Introduction of the Pt midlayer creates two additional Schottky barriers, which mediate the band bending potential at each metal-oxide interface and attains a rectifying current conduction at the high-resistance state. The rectifying conduction behavior is also observed with an AFM-tip as the top electrode, which implies the rectifying property is still valid when miniaturizing the device to nanometer scale. The current rectification consequently leads to a single-polarity, unipolar resistive switching and electrically rewritable performance for the TiOx/Pt/TiOx device.

Original languageEnglish
Pages (from-to)1918-1924
Number of pages7
JournalACS Applied Materials and Interfaces
Issue number6
Publication statusPublished - 2011 Jun 22

All Science Journal Classification (ASJC) codes

  • Materials Science(all)

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