Selective reductive defluorination of dicyclohexyl compounds: Intramolecular coupling reaction by reductive cleavage of C-F bonds

Kuangsen Sung; Richard J. Lagow

doi:10.1039/a708781k

Selective reductive defluorination of dicyclohexyl compounds: Intramolecular coupling reaction by reductive cleavage of C-F bonds

Kuangsen Sung, Richard J. Lagow

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

16 Citations (Scopus)

Abstract

Reductive defluorination of perfluoro(dicyclohexyl ether) 1 with benzophenone anion radical in tetrahydrofuran produces perfluoro(dibenzofuran) 2 with a surprising ring-closure, whereas reductive defluorination of perfluoro(dicyclohexyl) 4 under the same conditions gives perfluoro(diphenyl) 6 with no products involving ring-closure.

Original language	English
Pages (from-to)	637-638
Number of pages	2
Journal	Journal of the Chemical Society - Perkin Transactions 1
Issue number	4
DOIs	https://doi.org/10.1039/a708781k
Publication status	Published - 1998 Feb 21

All Science Journal Classification (ASJC) codes

General Chemistry

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title = "Selective reductive defluorination of dicyclohexyl compounds: Intramolecular coupling reaction by reductive cleavage of C-F bonds",

abstract = "Reductive defluorination of perfluoro(dicyclohexyl ether) 1 with benzophenone anion radical in tetrahydrofuran produces perfluoro(dibenzofuran) 2 with a surprising ring-closure, whereas reductive defluorination of perfluoro(dicyclohexyl) 4 under the same conditions gives perfluoro(diphenyl) 6 with no products involving ring-closure.",

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Selective reductive defluorination of dicyclohexyl compounds: Intramolecular coupling reaction by reductive cleavage of C-F bonds

Abstract

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