Simultaneous control of elemental mercury/sulfur dioxide/nitrogen monoxide from coal-fired flue gases with metal oxide-impregnated activated carbon

Chun Hsiang Chiu, Hong-Ping Lin, Tien Ho Kuo, Shiao Shing Chen, Tien Chin Chang, Kai Han Su, Hsing Cheng Hsi

Research output: Contribution to journalArticle

10 Citations (Scopus)

Abstract

This research investigated the effects of transition metal oxide impregnation on the physical/chemical properties and on the multipollutant (i.e., Hg0/SO2/NO) control of a commercial coconut shell-based activated carbon. V, Mn, and Cu oxides of 5 wt% as their precursor metal hydroxides were impregnated onto the activated carbon surface. After the transition metal oxide impregnation, the surface area and pore volume of activated carbon decreased. The surface morphology of activated carbons was similar prior to and after impregnation. Mn3+/Mn4+and Cu+/Cu2+ were shown to be the major valence states presenting in the MnOx and CuOx/CAC samples, respectively. CuOx/CAC possessed the greatest Hg0 removal efficiency of approximately 54.5% under N2 condition and 98.9% under flue gas condition, respectively at 150°C. When the gas temperature increased to 350°C, the metal oxide-impregnated activated carbon still possessed appreciable Hg0 removal, especially for CuOx/CAC. The VOx/CAC had the largest SO2 removal enhancement of approximately 28.3% at 350°C. The NO removal of raw and impregnated activated carbon was very small under flue gas condition, indicating that adsorption of NO using metal oxide-impregnated activated carbon may not be a suitable route for NO control.

Original languageEnglish
Pages (from-to)2094-2103
Number of pages10
JournalAerosol and Air Quality Research
Volume15
Issue number5
DOIs
Publication statusPublished - 2015 Oct 1

Fingerprint

Sulfur Dioxide
Coal
Sulfur dioxide
Mercury
Flue gases
sulfur dioxide
Activated carbon
Oxides
activated carbon
Nitric Oxide
Metals
coal
Nitrogen
Impregnation
transition element
Transition metals
Hydroxides
nitrogen monoxide
mercury
flue gas

All Science Journal Classification (ASJC) codes

  • Environmental Chemistry
  • Pollution

Cite this

Chiu, Chun Hsiang ; Lin, Hong-Ping ; Kuo, Tien Ho ; Chen, Shiao Shing ; Chang, Tien Chin ; Su, Kai Han ; Hsi, Hsing Cheng. / Simultaneous control of elemental mercury/sulfur dioxide/nitrogen monoxide from coal-fired flue gases with metal oxide-impregnated activated carbon. In: Aerosol and Air Quality Research. 2015 ; Vol. 15, No. 5. pp. 2094-2103.
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abstract = "This research investigated the effects of transition metal oxide impregnation on the physical/chemical properties and on the multipollutant (i.e., Hg0/SO2/NO) control of a commercial coconut shell-based activated carbon. V, Mn, and Cu oxides of 5 wt{\%} as their precursor metal hydroxides were impregnated onto the activated carbon surface. After the transition metal oxide impregnation, the surface area and pore volume of activated carbon decreased. The surface morphology of activated carbons was similar prior to and after impregnation. Mn3+/Mn4+and Cu+/Cu2+ were shown to be the major valence states presenting in the MnOx and CuOx/CAC samples, respectively. CuOx/CAC possessed the greatest Hg0 removal efficiency of approximately 54.5{\%} under N2 condition and 98.9{\%} under flue gas condition, respectively at 150°C. When the gas temperature increased to 350°C, the metal oxide-impregnated activated carbon still possessed appreciable Hg0 removal, especially for CuOx/CAC. The VOx/CAC had the largest SO2 removal enhancement of approximately 28.3{\%} at 350°C. The NO removal of raw and impregnated activated carbon was very small under flue gas condition, indicating that adsorption of NO using metal oxide-impregnated activated carbon may not be a suitable route for NO control.",
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Simultaneous control of elemental mercury/sulfur dioxide/nitrogen monoxide from coal-fired flue gases with metal oxide-impregnated activated carbon. / Chiu, Chun Hsiang; Lin, Hong-Ping; Kuo, Tien Ho; Chen, Shiao Shing; Chang, Tien Chin; Su, Kai Han; Hsi, Hsing Cheng.

In: Aerosol and Air Quality Research, Vol. 15, No. 5, 01.10.2015, p. 2094-2103.

Research output: Contribution to journalArticle

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AU - Chiu, Chun Hsiang

AU - Lin, Hong-Ping

AU - Kuo, Tien Ho

AU - Chen, Shiao Shing

AU - Chang, Tien Chin

AU - Su, Kai Han

AU - Hsi, Hsing Cheng

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AB - This research investigated the effects of transition metal oxide impregnation on the physical/chemical properties and on the multipollutant (i.e., Hg0/SO2/NO) control of a commercial coconut shell-based activated carbon. V, Mn, and Cu oxides of 5 wt% as their precursor metal hydroxides were impregnated onto the activated carbon surface. After the transition metal oxide impregnation, the surface area and pore volume of activated carbon decreased. The surface morphology of activated carbons was similar prior to and after impregnation. Mn3+/Mn4+and Cu+/Cu2+ were shown to be the major valence states presenting in the MnOx and CuOx/CAC samples, respectively. CuOx/CAC possessed the greatest Hg0 removal efficiency of approximately 54.5% under N2 condition and 98.9% under flue gas condition, respectively at 150°C. When the gas temperature increased to 350°C, the metal oxide-impregnated activated carbon still possessed appreciable Hg0 removal, especially for CuOx/CAC. The VOx/CAC had the largest SO2 removal enhancement of approximately 28.3% at 350°C. The NO removal of raw and impregnated activated carbon was very small under flue gas condition, indicating that adsorption of NO using metal oxide-impregnated activated carbon may not be a suitable route for NO control.

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