Soft solution processing for direct fabrication of LiMO2 (M=Ni and Co) film

Kyoo Seung Han; Seung Wan Song; Shunsuke Tsurimoto; Hirofumi Fujita; Itsuro Sasagawa; Kang Hong Choi; Hyun Koo Kang; Masahiro Yoshimura

doi:10.1016/S0167-2738(02)00598-2

Soft solution processing for direct fabrication of LiMO₂ (M=Ni and Co) film

Kyoo Seung Han, Seung Wan Song, Shunsuke Tsurimoto, Hirofumi Fujita, Itsuro Sasagawa, Kang Hong Choi, Hyun Koo Kang, Masahiro Yoshimura

Department of Materials Science and Engineering

Research output: Contribution to journal › Conference article › peer-review

14 Citations (Scopus)

Abstract

LiMO₂ (M=Ni and Co) films were directly fabricated in a concentrated LiOH solution at fixed temperatures, between 100 and 200 °C, using Soft Solution Processing. Film formation mechanism studies elucidate the key role of hydroxyl group in obtaining the LiCoO₂ films and of electrochemical anodic process in obtaining the LiNiO₂ films. It is also found that the formation of the LiMO₂ (M=Ni and Co) is fully based on dissolution-precipitation model. Successful preparation of LiMO₂ (M=Ni and Co) films using the newly designed experimental conditions based on the elucidation of the microstructuring mechanism shows a good example of how to introduce more economical, energy and material efficient, and environment-friendly synthetic route.

Original language	English
Pages (from-to)	11-18
Number of pages	8
Journal	Solid State Ionics
Volume	151
Issue number	1-4
DOIs	https://doi.org/10.1016/S0167-2738(02)00598-2
Publication status	Published - 2002 Nov
Event	SSP- 2000 - Tokyo, Japan Duration: 2000 Dec 11 → 2000 Dec 13

All Science Journal Classification (ASJC) codes

General Chemistry
General Materials Science
Condensed Matter Physics

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10.1016/S0167-2738(02)00598-2

Cite this

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title = "Soft solution processing for direct fabrication of LiMO2 (M=Ni and Co) film",

abstract = "LiMO2 (M=Ni and Co) films were directly fabricated in a concentrated LiOH solution at fixed temperatures, between 100 and 200 °C, using Soft Solution Processing. Film formation mechanism studies elucidate the key role of hydroxyl group in obtaining the LiCoO2 films and of electrochemical anodic process in obtaining the LiNiO2 films. It is also found that the formation of the LiMO2 (M=Ni and Co) is fully based on dissolution-precipitation model. Successful preparation of LiMO2 (M=Ni and Co) films using the newly designed experimental conditions based on the elucidation of the microstructuring mechanism shows a good example of how to introduce more economical, energy and material efficient, and environment-friendly synthetic route.",

author = "Han, {Kyoo Seung} and Song, {Seung Wan} and Shunsuke Tsurimoto and Hirofumi Fujita and Itsuro Sasagawa and Choi, {Kang Hong} and Kang, {Hyun Koo} and Masahiro Yoshimura",

year = "2002",

month = nov,

doi = "10.1016/S0167-2738(02)00598-2",

language = "English",

volume = "151",

pages = "11--18",

journal = "Solid State Ionics",

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note = "SSP- 2000 ; Conference date: 11-12-2000 Through 13-12-2000",

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TY - JOUR

T1 - Soft solution processing for direct fabrication of LiMO2 (M=Ni and Co) film

AU - Han, Kyoo Seung

AU - Song, Seung Wan

AU - Tsurimoto, Shunsuke

AU - Fujita, Hirofumi

AU - Sasagawa, Itsuro

AU - Choi, Kang Hong

AU - Kang, Hyun Koo

AU - Yoshimura, Masahiro

PY - 2002/11

Y1 - 2002/11

N2 - LiMO2 (M=Ni and Co) films were directly fabricated in a concentrated LiOH solution at fixed temperatures, between 100 and 200 °C, using Soft Solution Processing. Film formation mechanism studies elucidate the key role of hydroxyl group in obtaining the LiCoO2 films and of electrochemical anodic process in obtaining the LiNiO2 films. It is also found that the formation of the LiMO2 (M=Ni and Co) is fully based on dissolution-precipitation model. Successful preparation of LiMO2 (M=Ni and Co) films using the newly designed experimental conditions based on the elucidation of the microstructuring mechanism shows a good example of how to introduce more economical, energy and material efficient, and environment-friendly synthetic route.

AB - LiMO2 (M=Ni and Co) films were directly fabricated in a concentrated LiOH solution at fixed temperatures, between 100 and 200 °C, using Soft Solution Processing. Film formation mechanism studies elucidate the key role of hydroxyl group in obtaining the LiCoO2 films and of electrochemical anodic process in obtaining the LiNiO2 films. It is also found that the formation of the LiMO2 (M=Ni and Co) is fully based on dissolution-precipitation model. Successful preparation of LiMO2 (M=Ni and Co) films using the newly designed experimental conditions based on the elucidation of the microstructuring mechanism shows a good example of how to introduce more economical, energy and material efficient, and environment-friendly synthetic route.

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DO - 10.1016/S0167-2738(02)00598-2

M3 - Conference article

AN - SCOPUS:0036856492

SN - 0167-2738

VL - 151

SP - 11

EP - 18

JO - Solid State Ionics

JF - Solid State Ionics

IS - 1-4

T2 - SSP- 2000

Y2 - 11 December 2000 through 13 December 2000

ER -

Soft solution processing for direct fabrication of LiMO₂ (M=Ni and Co) film

Abstract

All Science Journal Classification (ASJC) codes

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