Spectroscopic and thermal properties of the copolymer of aniline with dithiodianiline

Ten Chin Wen; Li Ming Huang; A. Gopalan

doi:10.1016/S0379-6779(01)00337-X

Spectroscopic and thermal properties of the copolymer of aniline with dithiodianiline

Ten Chin Wen, Li Ming Huang, A. Gopalan

Department of Chemical Engineering

Research output: Contribution to journal › Article › peer-review

30 Citations (Scopus)

Abstract

Electrochemical copolymerization of aniline (ANI) with dithiodianiline (DTDA), an aniline derivative containing -S-S- links was carried out in 2M H₂SO₄ using cyclic voltammetry. The cyclicvoltamogram (CV) of the deposited copolymer was recorded in monomer free background electrolyte. A close comparison of the CV characteristics of the films deposited during polymerization of mixture of ANI and DTDA clearly the copolymer deposition. The UV-VIS spectroscopy, spectroelectrochemical studies, thermal analysis and FTIR spectroscopic analysis were used to identify the differences between the copolymer and PANI in the optical, thermal properties and structure. The copolymer was found to have a branched structure in comparison with PANI. The copolymer exhibit different colors upon changing applied potentials.

Original language	English
Pages (from-to)	451-457
Number of pages	7
Journal	Synthetic Metals
Volume	123
Issue number	3
DOIs	https://doi.org/10.1016/S0379-6779(01)00337-X
Publication status	Published - 2001 Sept 24

All Science Journal Classification (ASJC) codes

Electronic, Optical and Magnetic Materials
Condensed Matter Physics
Mechanics of Materials
Mechanical Engineering
Metals and Alloys
Materials Chemistry

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10.1016/S0379-6779(01)00337-X

Cite this

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title = "Spectroscopic and thermal properties of the copolymer of aniline with dithiodianiline",

abstract = "Electrochemical copolymerization of aniline (ANI) with dithiodianiline (DTDA), an aniline derivative containing -S-S- links was carried out in 2M H2SO4 using cyclic voltammetry. The cyclicvoltamogram (CV) of the deposited copolymer was recorded in monomer free background electrolyte. A close comparison of the CV characteristics of the films deposited during polymerization of mixture of ANI and DTDA clearly the copolymer deposition. The UV-VIS spectroscopy, spectroelectrochemical studies, thermal analysis and FTIR spectroscopic analysis were used to identify the differences between the copolymer and PANI in the optical, thermal properties and structure. The copolymer was found to have a branched structure in comparison with PANI. The copolymer exhibit different colors upon changing applied potentials.",

author = "Wen, {Ten Chin} and Huang, {Li Ming} and A. Gopalan",

note = "Funding Information: The authors are grateful to the National Science Council of Taiwan for its financial support through NSC 89-2214-E-006-048. ",

year = "2001",

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doi = "10.1016/S0379-6779(01)00337-X",

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TY - JOUR

T1 - Spectroscopic and thermal properties of the copolymer of aniline with dithiodianiline

AU - Wen, Ten Chin

AU - Huang, Li Ming

AU - Gopalan, A.

N1 - Funding Information: The authors are grateful to the National Science Council of Taiwan for its financial support through NSC 89-2214-E-006-048.

PY - 2001/9/24

Y1 - 2001/9/24

N2 - Electrochemical copolymerization of aniline (ANI) with dithiodianiline (DTDA), an aniline derivative containing -S-S- links was carried out in 2M H2SO4 using cyclic voltammetry. The cyclicvoltamogram (CV) of the deposited copolymer was recorded in monomer free background electrolyte. A close comparison of the CV characteristics of the films deposited during polymerization of mixture of ANI and DTDA clearly the copolymer deposition. The UV-VIS spectroscopy, spectroelectrochemical studies, thermal analysis and FTIR spectroscopic analysis were used to identify the differences between the copolymer and PANI in the optical, thermal properties and structure. The copolymer was found to have a branched structure in comparison with PANI. The copolymer exhibit different colors upon changing applied potentials.

AB - Electrochemical copolymerization of aniline (ANI) with dithiodianiline (DTDA), an aniline derivative containing -S-S- links was carried out in 2M H2SO4 using cyclic voltammetry. The cyclicvoltamogram (CV) of the deposited copolymer was recorded in monomer free background electrolyte. A close comparison of the CV characteristics of the films deposited during polymerization of mixture of ANI and DTDA clearly the copolymer deposition. The UV-VIS spectroscopy, spectroelectrochemical studies, thermal analysis and FTIR spectroscopic analysis were used to identify the differences between the copolymer and PANI in the optical, thermal properties and structure. The copolymer was found to have a branched structure in comparison with PANI. The copolymer exhibit different colors upon changing applied potentials.

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DO - 10.1016/S0379-6779(01)00337-X

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VL - 123

SP - 451

EP - 457

JO - Synthetic Metals

JF - Synthetic Metals

IS - 3

ER -

Spectroscopic and thermal properties of the copolymer of aniline with dithiodianiline

Abstract

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