Abstract
The Na2(3sσg)(4sσg) 23Σ+g state of Na2 has been observed and studied by cw perturbation-facilitated optical-optical double-resonance (PFOODR) spectroscopy for the first time. A single-mode dye laser and a Ti-sapphire laser served as the pump and the probe lasers, respectively. A total of 543 PFOODR excitation signals have been assigned to the 23Σ+g ← b3Π1u transitions. Absolute vibrational numbering was determined by counting nodes in the 23Σ+g → a3Σ+u bound-free spectra. Spectroscopic constants and the corresponding RKR potential energy curve are presented in this vsork. The values of Te, Re, and De, are found to be 25 551.237(49) cm-1, 3.53463(35) Å, and 6211.5(1) cm-1 respectively.
Original language | English |
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Pages (from-to) | 411-421 |
Number of pages | 11 |
Journal | Journal of molecular spectroscopy |
Volume | 160 |
Issue number | 2 |
DOIs | |
Publication status | Published - 1993 Aug |
All Science Journal Classification (ASJC) codes
- Atomic and Molecular Physics, and Optics
- Spectroscopy
- Physical and Theoretical Chemistry