TY - JOUR
T1 - Stabilization of copper sludge by high-temperature CuFe2O4 synthesis process
AU - Lu, Hsing Cheng
AU - Chang, Juu En
AU - Shih, Pai Haung
AU - Chiang, Li Choung
N1 - Funding Information:
The authors gratefully acknowledge the National Science Council, Taiwan for its financial supports for this study (Contract No: NSC 95-2221-E-006-280).
Copyright:
Copyright 2008 Elsevier B.V., All rights reserved.
PY - 2008/2/11
Y1 - 2008/2/11
N2 - Copper sludge was stabilized by high-temperature CuFe2O4 ferritization technique with different sintering temperature, isothermal time and Fe3+/M2+ molar ratio. Copper is stabilized by inserting the copper ion into the stable CuFe2O4 structure by ferritization. The result indicates that sintering temperature above 800 °C would be proper temperature range for CuFe2O4 synthesis. When the Fe3+/M2+ molar ratio of sludges are above the stoichiometric ratio of 2, copper ion in sludge would be stabilized and hence be kept from leaching out. From the result of relative XRD intensity ratio, the equilibrium of the ferritization reaction could be reached by prolonging the isothermal time to 10 h. Judging by the TCLP results, the optimum ferritization parameters are Fe3+/M2+ molar ratio equal to 3.5, sintering temperature at 800 °C and isothermal time above 10 h.
AB - Copper sludge was stabilized by high-temperature CuFe2O4 ferritization technique with different sintering temperature, isothermal time and Fe3+/M2+ molar ratio. Copper is stabilized by inserting the copper ion into the stable CuFe2O4 structure by ferritization. The result indicates that sintering temperature above 800 °C would be proper temperature range for CuFe2O4 synthesis. When the Fe3+/M2+ molar ratio of sludges are above the stoichiometric ratio of 2, copper ion in sludge would be stabilized and hence be kept from leaching out. From the result of relative XRD intensity ratio, the equilibrium of the ferritization reaction could be reached by prolonging the isothermal time to 10 h. Judging by the TCLP results, the optimum ferritization parameters are Fe3+/M2+ molar ratio equal to 3.5, sintering temperature at 800 °C and isothermal time above 10 h.
UR - http://www.scopus.com/inward/record.url?scp=38149063864&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=38149063864&partnerID=8YFLogxK
U2 - 10.1016/j.jhazmat.2007.04.130
DO - 10.1016/j.jhazmat.2007.04.130
M3 - Article
C2 - 17561343
AN - SCOPUS:38149063864
SN - 0304-3894
VL - 150
SP - 504
EP - 509
JO - Journal of Hazardous Materials
JF - Journal of Hazardous Materials
IS - 3
ER -