TY - GEN
T1 - Stepwise inhibition effect of multinitroxyl radicals on styrene polymerization
AU - Horng, Richard
AU - Lee, Shin Ku
N1 - Copyright:
Copyright 2013 Elsevier B.V., All rights reserved.
PY - 2013
Y1 - 2013
N2 - Several nitroxides are used for study of their inhibiting effect on styrene polymerization. These nitroxides contain different nitroxyl moieties within molecules. Molecules with multinitroxyl centers within a single molecule possess stepwise radical killing reactivity. Each of these nitroxyl centers exhibits slightly different inhibitory capabilities in terminating the growth of polymer chains. A kinetic model is developed to calculate individual inhibition constants for each molecule's nitroxyl center and to characterize their kinetic behavior.
AB - Several nitroxides are used for study of their inhibiting effect on styrene polymerization. These nitroxides contain different nitroxyl moieties within molecules. Molecules with multinitroxyl centers within a single molecule possess stepwise radical killing reactivity. Each of these nitroxyl centers exhibits slightly different inhibitory capabilities in terminating the growth of polymer chains. A kinetic model is developed to calculate individual inhibition constants for each molecule's nitroxyl center and to characterize their kinetic behavior.
UR - https://www.scopus.com/pages/publications/84887165501
UR - https://www.scopus.com/pages/publications/84887165501#tab=citedBy
U2 - 10.4028/www.scientific.net/AMM.440.31
DO - 10.4028/www.scientific.net/AMM.440.31
M3 - Conference contribution
AN - SCOPUS:84887165501
SN - 9783037859025
T3 - Applied Mechanics and Materials
SP - 31
EP - 36
BT - Advanced Materials and Sports Equipment Design
T2 - 2013 International Conference on Advanced Materials and Sports Equipment Design, AMSED 2013
Y2 - 21 September 2013 through 23 September 2013
ER -