Superionic phase transition in AgI embedded in molecular sieves

S. V. Baryshnikov, Cheng Tien, E. V. Charnaya, Min-Kai Lee, D. Michel, W. Böhlmann, N. P. Andriyanova

Research output: Contribution to journalArticle

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Abstract

Superionic AgI particles embedded in MCM-41 and SBA-15 molecular sieves with different pore sizes were studied using NMR and dielectric methods. The measurements confirmed that the structure of the confined particles did not change noticeably compared to that in bulk AgI. A regular increase in the temperature of the superionic phase transition with decreasing pore size was observed and treated on the basis of the Landau theory of thermodynamic size effects. The maximum increase found upon warming and cooling was about 10 and 8 K, respectively. The ionic conductivity in β-AgI under confinement was shown to be due to silver mobility on the particle surface.

Original languageEnglish
Article number025214
JournalJournal of Physics Condensed Matter
Volume20
Issue number2
DOIs
Publication statusPublished - 2008 Jan 16

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Molecular sieves
absorbents
Pore size
Phase transitions
Multicarrier modulation
Ionic conductivity
Silver
porosity
Nuclear magnetic resonance
Thermodynamics
Cooling
ion currents
silver
cooling
thermodynamics
nuclear magnetic resonance
heating
Temperature
temperature
SBA-15

All Science Journal Classification (ASJC) codes

  • Materials Science(all)
  • Condensed Matter Physics

Cite this

Baryshnikov, S. V., Tien, C., Charnaya, E. V., Lee, M-K., Michel, D., Böhlmann, W., & Andriyanova, N. P. (2008). Superionic phase transition in AgI embedded in molecular sieves. Journal of Physics Condensed Matter, 20(2), [025214]. https://doi.org/10.1088/0953-8984/20/02/025214
Baryshnikov, S. V. ; Tien, Cheng ; Charnaya, E. V. ; Lee, Min-Kai ; Michel, D. ; Böhlmann, W. ; Andriyanova, N. P. / Superionic phase transition in AgI embedded in molecular sieves. In: Journal of Physics Condensed Matter. 2008 ; Vol. 20, No. 2.
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Baryshnikov, SV, Tien, C, Charnaya, EV, Lee, M-K, Michel, D, Böhlmann, W & Andriyanova, NP 2008, 'Superionic phase transition in AgI embedded in molecular sieves', Journal of Physics Condensed Matter, vol. 20, no. 2, 025214. https://doi.org/10.1088/0953-8984/20/02/025214

Superionic phase transition in AgI embedded in molecular sieves. / Baryshnikov, S. V.; Tien, Cheng; Charnaya, E. V.; Lee, Min-Kai; Michel, D.; Böhlmann, W.; Andriyanova, N. P.

In: Journal of Physics Condensed Matter, Vol. 20, No. 2, 025214, 16.01.2008.

Research output: Contribution to journalArticle

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AU - Baryshnikov, S. V.

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AU - Böhlmann, W.

AU - Andriyanova, N. P.

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AB - Superionic AgI particles embedded in MCM-41 and SBA-15 molecular sieves with different pore sizes were studied using NMR and dielectric methods. The measurements confirmed that the structure of the confined particles did not change noticeably compared to that in bulk AgI. A regular increase in the temperature of the superionic phase transition with decreasing pore size was observed and treated on the basis of the Landau theory of thermodynamic size effects. The maximum increase found upon warming and cooling was about 10 and 8 K, respectively. The ionic conductivity in β-AgI under confinement was shown to be due to silver mobility on the particle surface.

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