SURFACE PROPERTIES OF LONG CHAIN ALKYL CROWN ETHERS.

Ping-Lin Kuo, Isao Ikeda, Mitsuo Okahara

Research output: Contribution to journalArticle

20 Citations (Scopus)

Abstract

The surface properties of long chain alkyl crown ethers (I), one of the most typical crown compounds, are investigated and compared with those of the corresponding open chain compounds (III), i. e. , homogeneous alkyl substituted polyethylene glycol, and N-alkyl monoaza crown ethers (II). I shows lower cloud point, far lower c. m. c. , and higher free energy change of adsorption ( DELTA G) than II. The higher steric effect of rigid ring structure for I compared to III can be recognized by the adsorption area at the air-aqueous solution interface. It can be concluded from the surface properties that I shows lower hydrophilicity than II due to the existence of nitrogen atom in the crown ring.

Original languageEnglish
Pages (from-to)204-206
Number of pages3
JournalTenside Detergents
Volume19
Issue number4
Publication statusPublished - 1982 Jan 1

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Crown Ethers
Crown ethers
Surface Properties
surface properties
Crown Compounds
Adsorption
Surface properties
ethers
adsorption
ring structures
Hydrophilicity
Crowns
Hydrophobic and Hydrophilic Interactions
nitrogen atoms
Polyethylene glycols
Free energy
glycols
polyethylenes
Nitrogen
free energy

All Science Journal Classification (ASJC) codes

  • Medicine(all)

Cite this

Kuo, P-L., Ikeda, I., & Okahara, M. (1982). SURFACE PROPERTIES OF LONG CHAIN ALKYL CROWN ETHERS. Tenside Detergents, 19(4), 204-206.
Kuo, Ping-Lin ; Ikeda, Isao ; Okahara, Mitsuo. / SURFACE PROPERTIES OF LONG CHAIN ALKYL CROWN ETHERS. In: Tenside Detergents. 1982 ; Vol. 19, No. 4. pp. 204-206.
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Kuo, P-L, Ikeda, I & Okahara, M 1982, 'SURFACE PROPERTIES OF LONG CHAIN ALKYL CROWN ETHERS.', Tenside Detergents, vol. 19, no. 4, pp. 204-206.

SURFACE PROPERTIES OF LONG CHAIN ALKYL CROWN ETHERS. / Kuo, Ping-Lin; Ikeda, Isao; Okahara, Mitsuo.

In: Tenside Detergents, Vol. 19, No. 4, 01.01.1982, p. 204-206.

Research output: Contribution to journalArticle

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AB - The surface properties of long chain alkyl crown ethers (I), one of the most typical crown compounds, are investigated and compared with those of the corresponding open chain compounds (III), i. e. , homogeneous alkyl substituted polyethylene glycol, and N-alkyl monoaza crown ethers (II). I shows lower cloud point, far lower c. m. c. , and higher free energy change of adsorption ( DELTA G) than II. The higher steric effect of rigid ring structure for I compared to III can be recognized by the adsorption area at the air-aqueous solution interface. It can be concluded from the surface properties that I shows lower hydrophilicity than II due to the existence of nitrogen atom in the crown ring.

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