Synergistic Effects of Binary-Solvent Annealing for Efficient Polymer-Fullerene Bulk Heterojunction Solar Cells

Fu Chiao Wu, Yi Hao Li, Chieh Jen Tsou, Kuo Cheng Tung, Chia Te Yen, Fang Sheng Chou, Fu Ching Tang, Wei Yang Chou, Jrjeng Ruan, Horng Long Cheng

Research output: Contribution to journalArticle

12 Citations (Scopus)

Abstract

Conjugated polymer-fullerene-based bulk-heterojunction (BHJ) organic solar cells (OSCs) have attracted tremendous attention over the past two decades because of their potential to develop low-cost and easy methods to produce energy from light. The complicated microstructure and morphology with randomly organized architecture of these polymer-fullerene-based active layers (ALs) is a key factor that limits photovoltaic performance. In this study, a binary-solvent annealing (BSA) approach was established to improve the poly(3-hexylthiophene):indene-C60 bisadduct-based AL for efficient BHJ-type OSCs by varying the second solvents with different boiling points (BP). Thus, we were able to change the evaporation behavior of cosolvents and consequently obtain the various microstructural properties of the AL. An in-depth study was conducted on the solvent-evaporation driven morphology of the active layer under various cosolvent conditions and its effect on the photovoltaic parameters of OSCs. Under the BSA processes, we found that the specimens with low-BP second solvents allows us to observe a more ideal AL for increasing photon absorption and efficient charge transport and collection at the respective electrodes, resulting in enhanced PCE of the corresponding OSCs. By contrast, the specimens with high-BP second solvents exhibit random microstructures, which are detrimental to charge transport and collection and lead to diminished PCE of the corresponding OSCs. By appropriately selecting the composition of a binary solvent, BSA can be employed as an easy method for the effective manipulation of the microstructures of ALs. BSA is a promising technique for the performance enhancement of not only OSCs but also other organic/polymeric-based electronic devices.

Original languageEnglish
Pages (from-to)18967-18976
Number of pages10
JournalACS Applied Materials and Interfaces
Volume7
Issue number34
DOIs
Publication statusPublished - 2015 Aug 12

Fingerprint

Fullerenes
Heterojunctions
Solar cells
Polymers
Annealing
Boiling point
Microstructure
Charge transfer
Evaporation
Conjugated polymers
Organic solar cells
Photons
Electrodes

All Science Journal Classification (ASJC) codes

  • Materials Science(all)

Cite this

Wu, Fu Chiao ; Li, Yi Hao ; Tsou, Chieh Jen ; Tung, Kuo Cheng ; Yen, Chia Te ; Chou, Fang Sheng ; Tang, Fu Ching ; Chou, Wei Yang ; Ruan, Jrjeng ; Cheng, Horng Long. / Synergistic Effects of Binary-Solvent Annealing for Efficient Polymer-Fullerene Bulk Heterojunction Solar Cells. In: ACS Applied Materials and Interfaces. 2015 ; Vol. 7, No. 34. pp. 18967-18976.
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abstract = "Conjugated polymer-fullerene-based bulk-heterojunction (BHJ) organic solar cells (OSCs) have attracted tremendous attention over the past two decades because of their potential to develop low-cost and easy methods to produce energy from light. The complicated microstructure and morphology with randomly organized architecture of these polymer-fullerene-based active layers (ALs) is a key factor that limits photovoltaic performance. In this study, a binary-solvent annealing (BSA) approach was established to improve the poly(3-hexylthiophene):indene-C60 bisadduct-based AL for efficient BHJ-type OSCs by varying the second solvents with different boiling points (BP). Thus, we were able to change the evaporation behavior of cosolvents and consequently obtain the various microstructural properties of the AL. An in-depth study was conducted on the solvent-evaporation driven morphology of the active layer under various cosolvent conditions and its effect on the photovoltaic parameters of OSCs. Under the BSA processes, we found that the specimens with low-BP second solvents allows us to observe a more ideal AL for increasing photon absorption and efficient charge transport and collection at the respective electrodes, resulting in enhanced PCE of the corresponding OSCs. By contrast, the specimens with high-BP second solvents exhibit random microstructures, which are detrimental to charge transport and collection and lead to diminished PCE of the corresponding OSCs. By appropriately selecting the composition of a binary solvent, BSA can be employed as an easy method for the effective manipulation of the microstructures of ALs. BSA is a promising technique for the performance enhancement of not only OSCs but also other organic/polymeric-based electronic devices.",
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Synergistic Effects of Binary-Solvent Annealing for Efficient Polymer-Fullerene Bulk Heterojunction Solar Cells. / Wu, Fu Chiao; Li, Yi Hao; Tsou, Chieh Jen; Tung, Kuo Cheng; Yen, Chia Te; Chou, Fang Sheng; Tang, Fu Ching; Chou, Wei Yang; Ruan, Jrjeng; Cheng, Horng Long.

In: ACS Applied Materials and Interfaces, Vol. 7, No. 34, 12.08.2015, p. 18967-18976.

Research output: Contribution to journalArticle

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AU - Tsou, Chieh Jen

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AU - Yen, Chia Te

AU - Chou, Fang Sheng

AU - Tang, Fu Ching

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AU - Cheng, Horng Long

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