Synthesis and characteristics of chiral polymers with camphanediol moieties

Jui-Hsiang Liu, Fu‐Ren ‐R Tsai, Yuh‐Chung ‐C Lai

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

Optically active exo,exo‐2,3‐camphanediol (CPO) was synthesized from (+)‐camphor. The chiral polymers poly(CPO‐co‐TDI) and poly(CPO‐co‐IPDI) were synthesized by step polymerization of chiral compound CPO with toluene‐2,4‐diisocyanate (TDI) and isophorone diisocyanate (IPDI). Effects of solvents, reaction time and temperature on the polymerization were investigated. To investigate the stereo structure of the chiral polymers, two kinds of model compounds, exo‐exo‐2,3‐bornylene N,N′‐diphenyldicarbamate and exo,exo‐2,3‐bornylene N,N′‐dipropyldicarbamate, related to the prepared polymers were synthesized. Chiroptical characteristics and stereo structures of the chiral polymers were investigated by using a circular dichroic spectrometer. Effects of temperature and solvents on the specific rotation of the chiral polymers were evaluated. The results obtained in this investigation suggest that the synthesized chiral polymers have no one‐handed helix conformation.

Original languageEnglish
Pages (from-to)35-45
Number of pages11
JournalDie Angewandte Makromolekulare Chemie
Volume231
Issue number1
DOIs
Publication statusPublished - 1995 Jan 1

Fingerprint

Polymers
Polymerization
Camphor
Conformations
Spectrometers
Temperature

All Science Journal Classification (ASJC) codes

  • Materials Science(all)

Cite this

Liu, Jui-Hsiang ; Tsai, Fu‐Ren ‐R ; Lai, Yuh‐Chung ‐C. / Synthesis and characteristics of chiral polymers with camphanediol moieties. In: Die Angewandte Makromolekulare Chemie. 1995 ; Vol. 231, No. 1. pp. 35-45.
@article{b4e7d94bb6bf449199f8e510570c65c1,
title = "Synthesis and characteristics of chiral polymers with camphanediol moieties",
abstract = "Optically active exo,exo‐2,3‐camphanediol (CPO) was synthesized from (+)‐camphor. The chiral polymers poly(CPO‐co‐TDI) and poly(CPO‐co‐IPDI) were synthesized by step polymerization of chiral compound CPO with toluene‐2,4‐diisocyanate (TDI) and isophorone diisocyanate (IPDI). Effects of solvents, reaction time and temperature on the polymerization were investigated. To investigate the stereo structure of the chiral polymers, two kinds of model compounds, exo‐exo‐2,3‐bornylene N,N′‐diphenyldicarbamate and exo,exo‐2,3‐bornylene N,N′‐dipropyldicarbamate, related to the prepared polymers were synthesized. Chiroptical characteristics and stereo structures of the chiral polymers were investigated by using a circular dichroic spectrometer. Effects of temperature and solvents on the specific rotation of the chiral polymers were evaluated. The results obtained in this investigation suggest that the synthesized chiral polymers have no one‐handed helix conformation.",
author = "Jui-Hsiang Liu and Tsai, {Fu‐Ren ‐R} and Lai, {Yuh‐Chung ‐C}",
year = "1995",
month = "1",
day = "1",
doi = "10.1002/apmc.1995.052310104",
language = "English",
volume = "231",
pages = "35--45",
journal = "Macromolecular Materials and Engineering",
issn = "1438-7492",
publisher = "Wiley-VCH Verlag",
number = "1",

}

Synthesis and characteristics of chiral polymers with camphanediol moieties. / Liu, Jui-Hsiang; Tsai, Fu‐Ren ‐R; Lai, Yuh‐Chung ‐C.

In: Die Angewandte Makromolekulare Chemie, Vol. 231, No. 1, 01.01.1995, p. 35-45.

Research output: Contribution to journalArticle

TY - JOUR

T1 - Synthesis and characteristics of chiral polymers with camphanediol moieties

AU - Liu, Jui-Hsiang

AU - Tsai, Fu‐Ren ‐R

AU - Lai, Yuh‐Chung ‐C

PY - 1995/1/1

Y1 - 1995/1/1

N2 - Optically active exo,exo‐2,3‐camphanediol (CPO) was synthesized from (+)‐camphor. The chiral polymers poly(CPO‐co‐TDI) and poly(CPO‐co‐IPDI) were synthesized by step polymerization of chiral compound CPO with toluene‐2,4‐diisocyanate (TDI) and isophorone diisocyanate (IPDI). Effects of solvents, reaction time and temperature on the polymerization were investigated. To investigate the stereo structure of the chiral polymers, two kinds of model compounds, exo‐exo‐2,3‐bornylene N,N′‐diphenyldicarbamate and exo,exo‐2,3‐bornylene N,N′‐dipropyldicarbamate, related to the prepared polymers were synthesized. Chiroptical characteristics and stereo structures of the chiral polymers were investigated by using a circular dichroic spectrometer. Effects of temperature and solvents on the specific rotation of the chiral polymers were evaluated. The results obtained in this investigation suggest that the synthesized chiral polymers have no one‐handed helix conformation.

AB - Optically active exo,exo‐2,3‐camphanediol (CPO) was synthesized from (+)‐camphor. The chiral polymers poly(CPO‐co‐TDI) and poly(CPO‐co‐IPDI) were synthesized by step polymerization of chiral compound CPO with toluene‐2,4‐diisocyanate (TDI) and isophorone diisocyanate (IPDI). Effects of solvents, reaction time and temperature on the polymerization were investigated. To investigate the stereo structure of the chiral polymers, two kinds of model compounds, exo‐exo‐2,3‐bornylene N,N′‐diphenyldicarbamate and exo,exo‐2,3‐bornylene N,N′‐dipropyldicarbamate, related to the prepared polymers were synthesized. Chiroptical characteristics and stereo structures of the chiral polymers were investigated by using a circular dichroic spectrometer. Effects of temperature and solvents on the specific rotation of the chiral polymers were evaluated. The results obtained in this investigation suggest that the synthesized chiral polymers have no one‐handed helix conformation.

UR - http://www.scopus.com/inward/record.url?scp=84985507339&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84985507339&partnerID=8YFLogxK

U2 - 10.1002/apmc.1995.052310104

DO - 10.1002/apmc.1995.052310104

M3 - Article

VL - 231

SP - 35

EP - 45

JO - Macromolecular Materials and Engineering

JF - Macromolecular Materials and Engineering

SN - 1438-7492

IS - 1

ER -