Synthesis and characterization of coordination polymers with interpenetrated frameworks

M(adipate)(1,2-bis(4-pyridyl)ethane) and M(adipate)(trans-1,2-bis(4-pyridyl)ethene), M=Co, Mn

Ju Hsiou Liao, Shi Hao Cheng, Hui-Lien Tsai, Chen I. Yang

Research output: Contribution to journalArticle

18 Citations (Scopus)

Abstract

Four novel coordination polymers: M(adipate)(1,2-bis(4-pyridyl)ethane) (1, 2) and M(adipate)(trans-1,2-bis(4-pyridyl)ethene) (3, 4), M=Co (1, 3) or Mn (2, 4), were synthesized by the self-assembly of Co2+ or Mn2+, adipate, and 1,2-bis(4-pyridyl)ethane or trans-1,2-bis(4-pyridyl)ethene. Their crystal structures were determined by X-ray diffraction, showing that they have similar structures. Each structure of 1-4 contains two sets of interpenetrated open frameworks, which are built by M(adipate) 2-D networks connected by N,N′-dipyridyl ligands. Magnetic studies indicate 1-4 follow Curie-Weiss law and become antiferromagnetic at low temperatures.

Original languageEnglish
Pages (from-to)1-6
Number of pages6
JournalInorganica Chimica Acta
Volume338
DOIs
Publication statusPublished - 2002 Oct 14

Fingerprint

Ethane
coordination polymers
ethane
Polymers
Curie-Weiss law
synthesis
Self assembly
self assembly
Crystal structure
Ligands
X ray diffraction
ligands
crystal structure
diffraction
X-Ray Diffraction
x rays
Temperature
adipic acid
1,2-bis(4-pyridyl)ethene

All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Inorganic Chemistry
  • Physical and Theoretical Chemistry
  • Materials Chemistry

Cite this

@article{38de25ac53014351aa377eedb7ab5b72,
title = "Synthesis and characterization of coordination polymers with interpenetrated frameworks: M(adipate)(1,2-bis(4-pyridyl)ethane) and M(adipate)(trans-1,2-bis(4-pyridyl)ethene), M=Co, Mn",
abstract = "Four novel coordination polymers: M(adipate)(1,2-bis(4-pyridyl)ethane) (1, 2) and M(adipate)(trans-1,2-bis(4-pyridyl)ethene) (3, 4), M=Co (1, 3) or Mn (2, 4), were synthesized by the self-assembly of Co2+ or Mn2+, adipate, and 1,2-bis(4-pyridyl)ethane or trans-1,2-bis(4-pyridyl)ethene. Their crystal structures were determined by X-ray diffraction, showing that they have similar structures. Each structure of 1-4 contains two sets of interpenetrated open frameworks, which are built by M(adipate) 2-D networks connected by N,N′-dipyridyl ligands. Magnetic studies indicate 1-4 follow Curie-Weiss law and become antiferromagnetic at low temperatures.",
author = "Liao, {Ju Hsiou} and Cheng, {Shi Hao} and Hui-Lien Tsai and Yang, {Chen I.}",
year = "2002",
month = "10",
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volume = "338",
pages = "1--6",
journal = "Inorganica Chimica Acta",
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publisher = "Elsevier BV",

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T1 - Synthesis and characterization of coordination polymers with interpenetrated frameworks

T2 - M(adipate)(1,2-bis(4-pyridyl)ethane) and M(adipate)(trans-1,2-bis(4-pyridyl)ethene), M=Co, Mn

AU - Liao, Ju Hsiou

AU - Cheng, Shi Hao

AU - Tsai, Hui-Lien

AU - Yang, Chen I.

PY - 2002/10/14

Y1 - 2002/10/14

N2 - Four novel coordination polymers: M(adipate)(1,2-bis(4-pyridyl)ethane) (1, 2) and M(adipate)(trans-1,2-bis(4-pyridyl)ethene) (3, 4), M=Co (1, 3) or Mn (2, 4), were synthesized by the self-assembly of Co2+ or Mn2+, adipate, and 1,2-bis(4-pyridyl)ethane or trans-1,2-bis(4-pyridyl)ethene. Their crystal structures were determined by X-ray diffraction, showing that they have similar structures. Each structure of 1-4 contains two sets of interpenetrated open frameworks, which are built by M(adipate) 2-D networks connected by N,N′-dipyridyl ligands. Magnetic studies indicate 1-4 follow Curie-Weiss law and become antiferromagnetic at low temperatures.

AB - Four novel coordination polymers: M(adipate)(1,2-bis(4-pyridyl)ethane) (1, 2) and M(adipate)(trans-1,2-bis(4-pyridyl)ethene) (3, 4), M=Co (1, 3) or Mn (2, 4), were synthesized by the self-assembly of Co2+ or Mn2+, adipate, and 1,2-bis(4-pyridyl)ethane or trans-1,2-bis(4-pyridyl)ethene. Their crystal structures were determined by X-ray diffraction, showing that they have similar structures. Each structure of 1-4 contains two sets of interpenetrated open frameworks, which are built by M(adipate) 2-D networks connected by N,N′-dipyridyl ligands. Magnetic studies indicate 1-4 follow Curie-Weiss law and become antiferromagnetic at low temperatures.

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JF - Inorganica Chimica Acta

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