Synthesis and characterization of coordination polymers with interpenetrated frameworks: M(adipate)(1,2-bis(4-pyridyl)ethane) and M(adipate)(trans-1,2-bis(4-pyridyl)ethene), M=Co, Mn

Ju Hsiou Liao, Shi Hao Cheng, Hui Lien Tsai, Chen I. Yang

Research output: Contribution to journalArticle

18 Citations (Scopus)

Abstract

Four novel coordination polymers: M(adipate)(1,2-bis(4-pyridyl)ethane) (1, 2) and M(adipate)(trans-1,2-bis(4-pyridyl)ethene) (3, 4), M=Co (1, 3) or Mn (2, 4), were synthesized by the self-assembly of Co2+ or Mn2+, adipate, and 1,2-bis(4-pyridyl)ethane or trans-1,2-bis(4-pyridyl)ethene. Their crystal structures were determined by X-ray diffraction, showing that they have similar structures. Each structure of 1-4 contains two sets of interpenetrated open frameworks, which are built by M(adipate) 2-D networks connected by N,N′-dipyridyl ligands. Magnetic studies indicate 1-4 follow Curie-Weiss law and become antiferromagnetic at low temperatures.

Original languageEnglish
Pages (from-to)1-6
Number of pages6
JournalInorganica Chimica Acta
Volume338
DOIs
Publication statusPublished - 2002 Oct 14

All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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