Synthesis and characterization of organic dyes containing various donors and acceptors

Tzi Yi Wu, Ming Hsiu Tsao, Fu Lin Chen, Shyh Gang Su, Cheng Wen Chang, Hong Paul Wang, Yuan Chung Lin, Wen Chung Ou-Yang, I. Wen Sun

Research output: Contribution to journalArticle

85 Citations (Scopus)

Abstract

New organic dyes comprising carbazole, iminodibenzyl, or phenothiazine moieties, respectively, as the electron donors, and cyanoacetic acid or acrylic acid moieties as the electron acceptors/anchoring groups were synthesized and characterized. The influence of heteroatoms on carbazole, iminodibenzyl and phenothiazine donors, and cyano-substitution on the acid acceptor is evidenced by spectral, electrochemical, photovoltaic experiments, and density functional theory calculations. The phenothiazine dyes show solar-energy-to-electricity conversion efficiency (η) of 3.46-5.53%, whereas carbazole and iminodibenzyl dyes show η of 2.43% and 3.49%, respectively.

Original languageEnglish
Pages (from-to)329-353
Number of pages25
JournalInternational journal of molecular sciences
Volume11
Issue number1
DOIs
Publication statusPublished - 2010 Jan

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Molecular Biology
  • Spectroscopy
  • Computer Science Applications
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

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