TY - JOUR
T1 - Synthesis and Optical Properties of Lead-Free Cesium Tin Halide Perovskite Quantum Rods with High-Performance Solar Cell Application
AU - Chen, Lin Jer
AU - Lee, Chia Rong
AU - Chuang, Yu Ju
AU - Wu, Zhao Han
AU - Chen, Chienyi
N1 - Funding Information:
The authors would like to thank the Ministry of Science and Technology, Taiwan (MOST) (Contract 103-2112-M-006-016-MY3), the Department of Photonics and the Advanced Optoelectronic Technology Center, National Cheng Kung University for supporting this research.
Publisher Copyright:
© 2016 American Chemical Society.
PY - 2016/12/15
Y1 - 2016/12/15
N2 - Herein, the fabrication of a lead-free cesium tin halide perovskite produced via a simple solvothermal process is reported for the first time. The resulting CsSnX3 (X = Cl, Br, and I) quantum rods show composition-tunable photoluminescence (PL) emissions over the entire visible spectral window (from 625 to 709 nm), as well as significant tunability of the optical properties. In this study, we demonstrate that through hybrid materials (CsSnX3) with different halides, the system can be tunable in terms of PL. By replacing the halide of the CsSnX3 quantum rods, a power conversion efficiency of 12.96% under AM 1.5 G has been achieved. This lead-free quantum rod replacement has demonstrated to be an effective method to create an absorber layer that increases light harvesting and charge collection for photovoltaic applications in its perovskite phase.
AB - Herein, the fabrication of a lead-free cesium tin halide perovskite produced via a simple solvothermal process is reported for the first time. The resulting CsSnX3 (X = Cl, Br, and I) quantum rods show composition-tunable photoluminescence (PL) emissions over the entire visible spectral window (from 625 to 709 nm), as well as significant tunability of the optical properties. In this study, we demonstrate that through hybrid materials (CsSnX3) with different halides, the system can be tunable in terms of PL. By replacing the halide of the CsSnX3 quantum rods, a power conversion efficiency of 12.96% under AM 1.5 G has been achieved. This lead-free quantum rod replacement has demonstrated to be an effective method to create an absorber layer that increases light harvesting and charge collection for photovoltaic applications in its perovskite phase.
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U2 - 10.1021/acs.jpclett.6b02344
DO - 10.1021/acs.jpclett.6b02344
M3 - Article
AN - SCOPUS:85006836973
SN - 1948-7185
VL - 7
SP - 5028
EP - 5035
JO - Journal of Physical Chemistry Letters
JF - Journal of Physical Chemistry Letters
IS - 24
ER -
