Synthesis and polymerization of a chiral methacrylate derivative containing 2-endo-acetyloxybornyl group

Jui-Hsiang Liu, Mau Ching Fang

Research output: Contribution to journalArticle

Abstract

A new chiral monomer, (+)-2-endo-acetyloxy-5-endo-bornyl methacrylate (ABMA), was synthesized. Homopolymerization of the ABMA and copolymerization of the chiral monomer with various achiral comonomers were carried out. It was found that only a trace of chiral homopolymer could be produced because of a large steric hindrance between ABMA monomers. The steric hindrance can be released by introducing a suitable comonomer as a low steric hindrance spacer into the polymer backbone. Monomer reactivity ratios for poly(ABMA-co-methyl methacrylate) and poly(ABMA-co-styrene), and resonance stabilization and polarity values for ABMA were also estimated.

Original languageEnglish
Pages (from-to)339-340
Number of pages2
JournalPolymer communications Guildford
Volume30
Issue number11
Publication statusPublished - 1989 Nov

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Methacrylates
Monomers
Polymerization
Derivatives
Homopolymerization
Copolymerization
Styrene
Stabilization
Polymethyl Methacrylate
Polymers

All Science Journal Classification (ASJC) codes

  • Engineering(all)

Cite this

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title = "Synthesis and polymerization of a chiral methacrylate derivative containing 2-endo-acetyloxybornyl group",
abstract = "A new chiral monomer, (+)-2-endo-acetyloxy-5-endo-bornyl methacrylate (ABMA), was synthesized. Homopolymerization of the ABMA and copolymerization of the chiral monomer with various achiral comonomers were carried out. It was found that only a trace of chiral homopolymer could be produced because of a large steric hindrance between ABMA monomers. The steric hindrance can be released by introducing a suitable comonomer as a low steric hindrance spacer into the polymer backbone. Monomer reactivity ratios for poly(ABMA-co-methyl methacrylate) and poly(ABMA-co-styrene), and resonance stabilization and polarity values for ABMA were also estimated.",
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Synthesis and polymerization of a chiral methacrylate derivative containing 2-endo-acetyloxybornyl group. / Liu, Jui-Hsiang; Fang, Mau Ching.

In: Polymer communications Guildford, Vol. 30, No. 11, 11.1989, p. 339-340.

Research output: Contribution to journalArticle

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