TY - JOUR
T1 - Synthesis and polymerization of chiral monomers containing dimethylaminobornane moieties
AU - Liu, Jui‐Hsiang ‐H
AU - Lin, Ming‐Ter ‐T
PY - 1993/7
Y1 - 1993/7
N2 - Chiral monomers (cis, endo‐3‐dimethylamino‐2‐bornyl methacrylate (DABM) and N, N‐dimethyl[cis,endo‐2‐(2‐vinyloxyethoxy)‐3‐bornyl]amine (DVEBA)) were synthesized from (+)‐camphor. The free radical homopolymerization of both DABM and DVEBA, and the copolymerization of both chiral monomers with achiral methyl methacrylate and styrene, resp., were carried out in various organic solvents. Effects of temperature, solvents, and reaction time on the polymerizations were studied. Dependences of the specific rotation of the chiral copolymers on the feed concentration and reaction conditions were investigated. Application of the chiral polymers on the asymmetric induction were also investigated.
AB - Chiral monomers (cis, endo‐3‐dimethylamino‐2‐bornyl methacrylate (DABM) and N, N‐dimethyl[cis,endo‐2‐(2‐vinyloxyethoxy)‐3‐bornyl]amine (DVEBA)) were synthesized from (+)‐camphor. The free radical homopolymerization of both DABM and DVEBA, and the copolymerization of both chiral monomers with achiral methyl methacrylate and styrene, resp., were carried out in various organic solvents. Effects of temperature, solvents, and reaction time on the polymerizations were studied. Dependences of the specific rotation of the chiral copolymers on the feed concentration and reaction conditions were investigated. Application of the chiral polymers on the asymmetric induction were also investigated.
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U2 - 10.1002/apmc.1993.052090115
DO - 10.1002/apmc.1993.052090115
M3 - Article
AN - SCOPUS:84985611236
SN - 0003-3146
VL - 209
SP - 167
EP - 177
JO - Die Angewandte Makromolekulare Chemie
JF - Die Angewandte Makromolekulare Chemie
IS - 1
ER -