Synthesis of CaALSIN3:Eu2+ phosphor via the self-propagating high temperature synthesis method and its optical properties

Shyan-Lung Chung, Shu Chi Huang

Research output: Chapter in Book/Report/Conference proceedingConference contribution

3 Citations (Scopus)

Abstract

A combustion synthesis method has been developed for synthesis of Eu2+ doped CaAlSiN3:Eu2+ phosphor and its photoluminescence properties were investigated. Ca, Al, Si, and Eu2O3 powders were used as the Ca, Al, Si, and Eu sources. NaN3 and NH4Cl were found necessary to be added for the formation of the product phase and addition of Si3N4 was found to enhance the product yield. These powders were mixed and pressed into a compact which was then wrapped up with an igniting agent (Mg+Fe3O4). The reactant compact was ignited by electrical heating under a N2 pressure of 0.8 MPa. The synthesized CaAlSiN3:Eu2+ phosphor absorbs light in the region of 240-520 nm and shows a broad band emission in the region of 500-800 nm due to the 4f65d1→4f7 transition of Eu2+. The synthesized phosphor thus has a potential application as a red phosphor for white LED lighting.

Original languageEnglish
Title of host publicationMaterial Science, Manufacturing Technology and Advanced Design Technology
PublisherTrans Tech Publications
Pages33-35
Number of pages3
ISBN (Print)9783038350460
DOIs
Publication statusPublished - 2014 Jan 1
Event3rd International Conference on Materials Science and Manufacturing, ICMSM 2014 - Yichang, China
Duration: 2014 Jan 102014 Jan 12

Publication series

NameAdvanced Materials Research
Volume904
ISSN (Print)1022-6680

Other

Other3rd International Conference on Materials Science and Manufacturing, ICMSM 2014
CountryChina
CityYichang
Period14-01-1014-01-12

Fingerprint

Phosphors
Optical properties
Powders
Temperature
Combustion synthesis
Light emitting diodes
Photoluminescence
Lighting
Heating

All Science Journal Classification (ASJC) codes

  • Engineering(all)

Cite this

Chung, S-L., & Huang, S. C. (2014). Synthesis of CaALSIN3:Eu2+ phosphor via the self-propagating high temperature synthesis method and its optical properties. In Material Science, Manufacturing Technology and Advanced Design Technology (pp. 33-35). (Advanced Materials Research; Vol. 904). Trans Tech Publications. https://doi.org/10.4028/www.scientific.net/AMR.904.33
Chung, Shyan-Lung ; Huang, Shu Chi. / Synthesis of CaALSIN3:Eu2+ phosphor via the self-propagating high temperature synthesis method and its optical properties. Material Science, Manufacturing Technology and Advanced Design Technology. Trans Tech Publications, 2014. pp. 33-35 (Advanced Materials Research).
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Chung, S-L & Huang, SC 2014, Synthesis of CaALSIN3:Eu2+ phosphor via the self-propagating high temperature synthesis method and its optical properties. in Material Science, Manufacturing Technology and Advanced Design Technology. Advanced Materials Research, vol. 904, Trans Tech Publications, pp. 33-35, 3rd International Conference on Materials Science and Manufacturing, ICMSM 2014, Yichang, China, 14-01-10. https://doi.org/10.4028/www.scientific.net/AMR.904.33

Synthesis of CaALSIN3:Eu2+ phosphor via the self-propagating high temperature synthesis method and its optical properties. / Chung, Shyan-Lung; Huang, Shu Chi.

Material Science, Manufacturing Technology and Advanced Design Technology. Trans Tech Publications, 2014. p. 33-35 (Advanced Materials Research; Vol. 904).

Research output: Chapter in Book/Report/Conference proceedingConference contribution

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N2 - A combustion synthesis method has been developed for synthesis of Eu2+ doped CaAlSiN3:Eu2+ phosphor and its photoluminescence properties were investigated. Ca, Al, Si, and Eu2O3 powders were used as the Ca, Al, Si, and Eu sources. NaN3 and NH4Cl were found necessary to be added for the formation of the product phase and addition of Si3N4 was found to enhance the product yield. These powders were mixed and pressed into a compact which was then wrapped up with an igniting agent (Mg+Fe3O4). The reactant compact was ignited by electrical heating under a N2 pressure of 0.8 MPa. The synthesized CaAlSiN3:Eu2+ phosphor absorbs light in the region of 240-520 nm and shows a broad band emission in the region of 500-800 nm due to the 4f65d1→4f7 transition of Eu2+. The synthesized phosphor thus has a potential application as a red phosphor for white LED lighting.

AB - A combustion synthesis method has been developed for synthesis of Eu2+ doped CaAlSiN3:Eu2+ phosphor and its photoluminescence properties were investigated. Ca, Al, Si, and Eu2O3 powders were used as the Ca, Al, Si, and Eu sources. NaN3 and NH4Cl were found necessary to be added for the formation of the product phase and addition of Si3N4 was found to enhance the product yield. These powders were mixed and pressed into a compact which was then wrapped up with an igniting agent (Mg+Fe3O4). The reactant compact was ignited by electrical heating under a N2 pressure of 0.8 MPa. The synthesized CaAlSiN3:Eu2+ phosphor absorbs light in the region of 240-520 nm and shows a broad band emission in the region of 500-800 nm due to the 4f65d1→4f7 transition of Eu2+. The synthesized phosphor thus has a potential application as a red phosphor for white LED lighting.

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Chung S-L, Huang SC. Synthesis of CaALSIN3:Eu2+ phosphor via the self-propagating high temperature synthesis method and its optical properties. In Material Science, Manufacturing Technology and Advanced Design Technology. Trans Tech Publications. 2014. p. 33-35. (Advanced Materials Research). https://doi.org/10.4028/www.scientific.net/AMR.904.33