Synthesis of chiral polymers with pendant aminobornanol derivatives

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Abstract

A series of diastereoisomeric amino bicyclo [2,2,1] heptane derivatives was synthesized from ( + )‐camphor. Further treatment of aminobornanols with triethyl orthopropionate yielded chiral oxazolines, which were found to be efficient for the asymmetric induction of carboxylic acids. Synthesis and polymerization of the new chiral oxazolinebornyl methacrylates derived from aminobornanols was carried out. Effects of temperature, solvents, and molar ratio of the reagent on the synthesis of the linear chiral and of the insoluble cross‐linked chiral polymers were also discussed.

Original languageEnglish
Pages (from-to)83-92
Number of pages10
JournalDie Angewandte Makromolekulare Chemie
Volume155
Issue number1
DOIs
Publication statusPublished - 1987 Nov

All Science Journal Classification (ASJC) codes

  • Materials Science(all)

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