Synthesis of copolyfluorenes with high fluorenone contents and its application in electroluminescent device by simple blending

Jyun Ru Wu, Yun Chen, Tzi Yi Wu

Research output: Contribution to journalArticle

8 Citations (Scopus)

Abstract

Poly(fluorene-co-fluorenone)s containing high contents of fluorenone chromophore were synthesized by the Suzuki coupling reaction to study their electroluminescent (EL) properties. The copolymers are thermally stable below 430°C (Td) in nitrogen atmosphere. In film state, their absorption and photoluminescence spectra (peaked at 373-382 nm and 562-564 nm, respectively) are mainly originated from fluorenone units, because of its efficient energy transfer. Both LUMO and HOMO energy levels, estimated from their cyclic voltammograms, are lowered slightly (-3.17→-3.23 eV, -5.84→-5.89 eV) with increasing contents of electron-withdrawing fluorenone units. Double-layer EL devices, using the copolyfluorenes or their blends with poly(9,9-dihexylfluorene) (PF) as emitting layer, show exclusive emission originated from fluorenone chromophore (565 nm) when its content is high. Blending 0.02-5 wt % of PF-33 (fluorenone fraction: 0.37) with PF greatly enhances device performance (610 cd m-2 → 4400 cd m-2 and 0.45 cd A-1 → 1.52 cd A-1). Our results demonstrate that the copolyfluorenes are promising emitting materials for EL devices by simple blending.

Original languageEnglish
Pages (from-to)2576-2583
Number of pages8
JournalJournal of Applied Polymer Science
Volume119
Issue number5
DOIs
Publication statusPublished - 2011 Mar 5

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Luminescent devices
Chromophores
Energy transfer
Electron energy levels
Photoluminescence
Nitrogen
Copolymers
Electrons
fluorene

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Polymers and Plastics
  • Materials Chemistry

Cite this

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title = "Synthesis of copolyfluorenes with high fluorenone contents and its application in electroluminescent device by simple blending",
abstract = "Poly(fluorene-co-fluorenone)s containing high contents of fluorenone chromophore were synthesized by the Suzuki coupling reaction to study their electroluminescent (EL) properties. The copolymers are thermally stable below 430°C (Td) in nitrogen atmosphere. In film state, their absorption and photoluminescence spectra (peaked at 373-382 nm and 562-564 nm, respectively) are mainly originated from fluorenone units, because of its efficient energy transfer. Both LUMO and HOMO energy levels, estimated from their cyclic voltammograms, are lowered slightly (-3.17→-3.23 eV, -5.84→-5.89 eV) with increasing contents of electron-withdrawing fluorenone units. Double-layer EL devices, using the copolyfluorenes or their blends with poly(9,9-dihexylfluorene) (PF) as emitting layer, show exclusive emission originated from fluorenone chromophore (565 nm) when its content is high. Blending 0.02-5 wt {\%} of PF-33 (fluorenone fraction: 0.37) with PF greatly enhances device performance (610 cd m-2 → 4400 cd m-2 and 0.45 cd A-1 → 1.52 cd A-1). Our results demonstrate that the copolyfluorenes are promising emitting materials for EL devices by simple blending.",
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Synthesis of copolyfluorenes with high fluorenone contents and its application in electroluminescent device by simple blending. / Wu, Jyun Ru; Chen, Yun; Wu, Tzi Yi.

In: Journal of Applied Polymer Science, Vol. 119, No. 5, 05.03.2011, p. 2576-2583.

Research output: Contribution to journalArticle

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