Synthesis of SiV-diamond particulates via the microwave plasma chemical deposition of ultrananocrystalline diamond on soda-lime glass fibers

Srinivasu Kunuku, Yen Chun Chen, Chien Jui Yeh, Wen Hao Chang, Divinah Manoharan, Keh Chyang Leou, I. Nan Lin

Research output: Contribution to journalArticlepeer-review

2 Citations (Scopus)

Abstract

Wereport the synthesis of silicon-vacancy (SiV) incorporated spherical shaped ultrananocrystalline diamond (SiV-UNCD) particulates (size∼1 μm) with bright luminescence at 738 nm. For this purpose, different granular structured polycrystalline diamond films and particulates were synthesized by using three different kinds of growth plasma conditions on the three types of substrate materials in the microwave plasma enhancedCVDprocess. The grain size dependent photoluminescence properties of nitrogen vacancy (NV) and SiV color centers have been investigated for different granular structured diamond samples. The luminescence ofNVcenter and the associated phonon sidebands, which are usually observed in microcrystalline diamond and nanocrystalline diamond films, were effectively suppressed inUNCDfilms andUNCDparticulates. Micron sized SiV-UNCD particulates with bright SiV emission has been attained by transfer of SiV-UNCD clusters on sodalime glass fibers to inverted pyramidal cavities fabricated on Si substrates by the simple crushing of UNCD/soda-lime glass fibers in deionized water and ultrasonication. Such a plasma enhancedCVD process for synthesizing SiV-UNCD particulates with suppressedNVemission is simple and robust to attain the bright SiV-UNCD particulates to employ in practical applications.

Original languageEnglish
Article number106205
JournalMaterials Research Express
Volume3
Issue number10
DOIs
Publication statusPublished - 2016 Oct

All Science Journal Classification (ASJC) codes

  • Electronic, Optical and Magnetic Materials
  • Biomaterials
  • Surfaces, Coatings and Films
  • Polymers and Plastics
  • Metals and Alloys

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