Synthesis of ZSM-type zeolites from rice husk ashes

Kuen Song Lin; Paul Wang; M. C. Li; L. K. Huang; Chun Yin Hwang; Y. J. Huang

Synthesis of ZSM-type zeolites from rice husk ashes

Kuen Song Lin, Paul Wang, M. C. Li, L. K. Huang, Chun Yin Hwang, Y. J. Huang

Department of Environmental Engineering

Research output: Contribution to journal › Conference article › peer-review

Abstract

High crystallinity (99%⁺) zeolites ZSM-5 and ZSM-48 synthesized from a reaction mixtures containing a silica source from ashes of rice husk gasification were investigated. XRD data indicates ZSM-5 and ZSM-48 with a high crystallinity can be obtained at a 48-hour crystallization time in the high pressure autoclave at 443 K. Experimentally, methanol conversion over the synthesized ZSM-5 and ZSM-48 has a high selectivity for aromatics and aliphatics, respectively. Diffuse reflectance infrared spectra reveal that benzene and pyridine molecules adsorb preferentially on the most energetic (Bronsted acid) sites first. The adsorbed benzene molecule is only slightly perturb from the D_6h selection rules for the free molecule.

Original language	English
Journal	Proceedings of the International Conference on Solid Waste Technology and Management
Volume	1
Publication status	Published - 1997
Event	Proceedings of the 1997 13th International Conference on Solid Waste Technology and Management. Part 1 (of 2) - Philadelphia, PA, USA Duration: 1997 Nov 16 → 1997 Nov 19

All Science Journal Classification (ASJC) codes

Environmental Engineering
Waste Management and Disposal

Cite this

@article{ddcb147f806b465393f197ed6dda0247,

title = "Synthesis of ZSM-type zeolites from rice husk ashes",

abstract = "High crystallinity (99%+) zeolites ZSM-5 and ZSM-48 synthesized from a reaction mixtures containing a silica source from ashes of rice husk gasification were investigated. XRD data indicates ZSM-5 and ZSM-48 with a high crystallinity can be obtained at a 48-hour crystallization time in the high pressure autoclave at 443 K. Experimentally, methanol conversion over the synthesized ZSM-5 and ZSM-48 has a high selectivity for aromatics and aliphatics, respectively. Diffuse reflectance infrared spectra reveal that benzene and pyridine molecules adsorb preferentially on the most energetic (Bronsted acid) sites first. The adsorbed benzene molecule is only slightly perturb from the D6h selection rules for the free molecule.",

author = "Lin, {Kuen Song} and Paul Wang and Li, {M. C.} and Huang, {L. K.} and Hwang, {Chun Yin} and Huang, {Y. J.}",

year = "1997",

language = "English",

volume = "1",

journal = "Proceedings of the International Conference on Solid Waste Technology and Management",

issn = "1091-8043",

note = "Proceedings of the 1997 13th International Conference on Solid Waste Technology and Management. Part 1 (of 2) ; Conference date: 16-11-1997 Through 19-11-1997",

}

TY - JOUR

T1 - Synthesis of ZSM-type zeolites from rice husk ashes

AU - Lin, Kuen Song

AU - Wang, Paul

AU - Li, M. C.

AU - Huang, L. K.

AU - Hwang, Chun Yin

AU - Huang, Y. J.

PY - 1997

Y1 - 1997

N2 - High crystallinity (99%+) zeolites ZSM-5 and ZSM-48 synthesized from a reaction mixtures containing a silica source from ashes of rice husk gasification were investigated. XRD data indicates ZSM-5 and ZSM-48 with a high crystallinity can be obtained at a 48-hour crystallization time in the high pressure autoclave at 443 K. Experimentally, methanol conversion over the synthesized ZSM-5 and ZSM-48 has a high selectivity for aromatics and aliphatics, respectively. Diffuse reflectance infrared spectra reveal that benzene and pyridine molecules adsorb preferentially on the most energetic (Bronsted acid) sites first. The adsorbed benzene molecule is only slightly perturb from the D6h selection rules for the free molecule.

AB - High crystallinity (99%+) zeolites ZSM-5 and ZSM-48 synthesized from a reaction mixtures containing a silica source from ashes of rice husk gasification were investigated. XRD data indicates ZSM-5 and ZSM-48 with a high crystallinity can be obtained at a 48-hour crystallization time in the high pressure autoclave at 443 K. Experimentally, methanol conversion over the synthesized ZSM-5 and ZSM-48 has a high selectivity for aromatics and aliphatics, respectively. Diffuse reflectance infrared spectra reveal that benzene and pyridine molecules adsorb preferentially on the most energetic (Bronsted acid) sites first. The adsorbed benzene molecule is only slightly perturb from the D6h selection rules for the free molecule.

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M3 - Conference article

AN - SCOPUS:0031340712

SN - 1091-8043

VL - 1

JO - Proceedings of the International Conference on Solid Waste Technology and Management

JF - Proceedings of the International Conference on Solid Waste Technology and Management

T2 - Proceedings of the 1997 13th International Conference on Solid Waste Technology and Management. Part 1 (of 2)

Y2 - 16 November 1997 through 19 November 1997

ER -

Synthesis of ZSM-type zeolites from rice husk ashes

Abstract

All Science Journal Classification (ASJC) codes

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