Tacticity effects on glass transition and phase behavior in binary blends of poly(methyl methacrylate)s of three different configurations

Ling Chang, Eamor Woo

Research output: Contribution to journalArticle

13 Citations (Scopus)

Abstract

Using optical and scanning electron microscopies, dynamic mechanical analysis, and differential scanning calorimetry, this study investigated effects of tacticity in PMMAs on the phase behavior in three pairs of binary blends comprising any two of isotactic-, syndiotactic-, and atactic-PMMAs. Miscibility was confirmed for all three binary blends (i.e., aPMMA/iPMMA, aPMMA/sPMMA, and iPMMA/sPMMA); however, the Tgvs. composition relationships for the aPMMA/iPMMA blend differ significantly. Configurational tacticity may lead to subtle differences in molecular interactions in the tactic polymers; and in turn such difference in the interactions causes variation in the glass transition and phase behavior in these three blends. This study also points out that the miscibility nature in iPMMA/sPMMA may constitute a prerequisite condition (necessary but not sufficient) for its tendency in forming complexes.

Original languageEnglish
Pages (from-to)198-202
Number of pages5
JournalPolymer Chemistry
Volume1
Issue number2
DOIs
Publication statusPublished - 2010 Apr 1

Fingerprint

Phase Transition
Polymethyl Methacrylate
Phase behavior
Polymethyl methacrylates
Glass
Glass transition
Solubility
Molecular interactions
Differential Scanning Calorimetry
Dynamic mechanical analysis
Electron Scanning Microscopy
Differential scanning calorimetry
Polymers
Scanning electron microscopy
Chemical analysis

All Science Journal Classification (ASJC) codes

  • Bioengineering
  • Biochemistry
  • Polymers and Plastics
  • Organic Chemistry

Cite this

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abstract = "Using optical and scanning electron microscopies, dynamic mechanical analysis, and differential scanning calorimetry, this study investigated effects of tacticity in PMMAs on the phase behavior in three pairs of binary blends comprising any two of isotactic-, syndiotactic-, and atactic-PMMAs. Miscibility was confirmed for all three binary blends (i.e., aPMMA/iPMMA, aPMMA/sPMMA, and iPMMA/sPMMA); however, the Tgvs. composition relationships for the aPMMA/iPMMA blend differ significantly. Configurational tacticity may lead to subtle differences in molecular interactions in the tactic polymers; and in turn such difference in the interactions causes variation in the glass transition and phase behavior in these three blends. This study also points out that the miscibility nature in iPMMA/sPMMA may constitute a prerequisite condition (necessary but not sufficient) for its tendency in forming complexes.",
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Tacticity effects on glass transition and phase behavior in binary blends of poly(methyl methacrylate)s of three different configurations. / Chang, Ling; Woo, Eamor.

In: Polymer Chemistry, Vol. 1, No. 2, 01.04.2010, p. 198-202.

Research output: Contribution to journalArticle

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