Tetra-butyl-ammonium bis-[4,4′-dimethyl-2,2′-(3,7-dimethyl-1H- 4,2,1-benzothiaza-siline-1,1-diyl)dibenzene-thiol-ato]vanadium(III) acetonitrile tetrasolvate

Yi Fang Tsai, Hua-Fen Hsu, Kuei-Fang Hsu, Ju Chun Wang

Research output: Contribution to journalArticle

Abstract

In the title compound, [N(C4H9)4][V(C 23H21NS3Si)2]·4CH 3CN, the VIII atom (site symmetry ) is coordinated by two N,S,S′-tridentate 4,4′-dimethyl-2,2′-(3,7-dimethyl-1H-4,2,1- benzothiaza-siline-1,1-diyl)dibenzene-thiol-ate ligands in a distorted trans-VN2S4 octa-hedral geometry. The complete cation is generated by crystallographic twofold symmetry, with the V atom lying on the rotation axis. The unusual ligand arose from nucleophilic attack on the coordinated nitrile by the thiol-ate precursor and reduction of nitrile to the imidate.

Original languageEnglish
JournalActa Crystallographica Section E: Structure Reports Online
Volume66
Issue number7
DOIs
Publication statusPublished - 2010 Jul 14

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Vanadium
Nitriles
nitriles
Acetonitrile
Ammonium Compounds
Sulfhydryl Compounds
thiols
vanadium
acetonitrile
Imidoesters
Ligands
Atoms
ligands
symmetry
attack
atoms
Cations
Positive ions
cations
Geometry

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

Cite this

@article{e5c01d4e3b5e4ae0aff7b15eee6def6d,
title = "Tetra-butyl-ammonium bis-[4,4′-dimethyl-2,2′-(3,7-dimethyl-1H- 4,2,1-benzothiaza-siline-1,1-diyl)dibenzene-thiol-ato]vanadium(III) acetonitrile tetrasolvate",
abstract = "In the title compound, [N(C4H9)4][V(C 23H21NS3Si)2]·4CH 3CN, the VIII atom (site symmetry ) is coordinated by two N,S,S′-tridentate 4,4′-dimethyl-2,2′-(3,7-dimethyl-1H-4,2,1- benzothiaza-siline-1,1-diyl)dibenzene-thiol-ate ligands in a distorted trans-VN2S4 octa-hedral geometry. The complete cation is generated by crystallographic twofold symmetry, with the V atom lying on the rotation axis. The unusual ligand arose from nucleophilic attack on the coordinated nitrile by the thiol-ate precursor and reduction of nitrile to the imidate.",
author = "Tsai, {Yi Fang} and Hua-Fen Hsu and Kuei-Fang Hsu and Wang, {Ju Chun}",
year = "2010",
month = "7",
day = "14",
doi = "10.1107/S1600536810022014",
language = "English",
volume = "66",
journal = "Acta Crystallographica Section E: Structure Reports Online",
issn = "1600-5368",
publisher = "International Union of Crystallography",
number = "7",

}

TY - JOUR

T1 - Tetra-butyl-ammonium bis-[4,4′-dimethyl-2,2′-(3,7-dimethyl-1H- 4,2,1-benzothiaza-siline-1,1-diyl)dibenzene-thiol-ato]vanadium(III) acetonitrile tetrasolvate

AU - Tsai, Yi Fang

AU - Hsu, Hua-Fen

AU - Hsu, Kuei-Fang

AU - Wang, Ju Chun

PY - 2010/7/14

Y1 - 2010/7/14

N2 - In the title compound, [N(C4H9)4][V(C 23H21NS3Si)2]·4CH 3CN, the VIII atom (site symmetry ) is coordinated by two N,S,S′-tridentate 4,4′-dimethyl-2,2′-(3,7-dimethyl-1H-4,2,1- benzothiaza-siline-1,1-diyl)dibenzene-thiol-ate ligands in a distorted trans-VN2S4 octa-hedral geometry. The complete cation is generated by crystallographic twofold symmetry, with the V atom lying on the rotation axis. The unusual ligand arose from nucleophilic attack on the coordinated nitrile by the thiol-ate precursor and reduction of nitrile to the imidate.

AB - In the title compound, [N(C4H9)4][V(C 23H21NS3Si)2]·4CH 3CN, the VIII atom (site symmetry ) is coordinated by two N,S,S′-tridentate 4,4′-dimethyl-2,2′-(3,7-dimethyl-1H-4,2,1- benzothiaza-siline-1,1-diyl)dibenzene-thiol-ate ligands in a distorted trans-VN2S4 octa-hedral geometry. The complete cation is generated by crystallographic twofold symmetry, with the V atom lying on the rotation axis. The unusual ligand arose from nucleophilic attack on the coordinated nitrile by the thiol-ate precursor and reduction of nitrile to the imidate.

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U2 - 10.1107/S1600536810022014

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