Tetra-butyl-ammonium bis-[4,4′-dimethyl-2,2′-(3,7-dimethyl-1H- 4,2,1-benzothiaza-siline-1,1-diyl)dibenzene-thiol-ato]vanadium(III) acetonitrile tetrasolvate

Yi Fang Tsai, Hua Fen Hsu, Kuei Fang Hsu, Ju Chun Wang

Research output: Contribution to journalArticlepeer-review

Abstract

In the title compound, [N(C4H9)4][V(C 23H21NS3Si)2]·4CH 3CN, the VIII atom (site symmetry ) is coordinated by two N,S,S′-tridentate 4,4′-dimethyl-2,2′-(3,7-dimethyl-1H-4,2,1- benzothiaza-siline-1,1-diyl)dibenzene-thiol-ate ligands in a distorted trans-VN2S4 octa-hedral geometry. The complete cation is generated by crystallographic twofold symmetry, with the V atom lying on the rotation axis. The unusual ligand arose from nucleophilic attack on the coordinated nitrile by the thiol-ate precursor and reduction of nitrile to the imidate.

Original languageEnglish
Pages (from-to)m844
JournalActa Crystallographica Section E: Structure Reports Online
Volume66
Issue number7
DOIs
Publication statusPublished - 2010

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

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