In the title compound, [N(C4H9)4][V(C 23H21NS3Si)2]·4CH 3CN, the VIII atom (site symmetry ) is coordinated by two N,S,S′-tridentate 4,4′-dimethyl-2,2′-(3,7-dimethyl-1H-4,2,1- benzothiaza-siline-1,1-diyl)dibenzene-thiol-ate ligands in a distorted trans-VN2S4 octa-hedral geometry. The complete cation is generated by crystallographic twofold symmetry, with the V atom lying on the rotation axis. The unusual ligand arose from nucleophilic attack on the coordinated nitrile by the thiol-ate precursor and reduction of nitrile to the imidate.
|Journal||Acta Crystallographica Section E: Structure Reports Online|
|Publication status||Published - 2010|
All Science Journal Classification (ASJC) codes
- Materials Science(all)
- Condensed Matter Physics