TY - JOUR
T1 - Tetragonal—Monoclinic Phase Transition Enthalpy and Temperature of ZrO2‐CeO2 Solid Solutions
AU - Yashima, Masatomo
AU - Mitsuhashi, Takefumi
AU - Takashina, Hiroyuki
AU - Kakihana, Masato
AU - Ikegami, Takayasu
AU - Yoshimura, Masahiro
PY - 1995/8
Y1 - 1995/8
N2 - DSC (differential scanning calorimeter) measurements were performed to investigate the tetragonal‐monoclinic (t‐m) transition enthalpy of the compositionally homogeneous ZrO2‐X mol% CeO2 solid solution of X= 0, 4, 8, and 12. The transition enthalpy decreases linearly with an increase of CeO2 content. The m → t transition enthalpy on heating agreed well with the inverse t → m one obtained during cooling. With increasing X, the DSC peak broadens and the transition temperature distribution of each sample increases, while the thermal hysteresis is almost independent of X.
AB - DSC (differential scanning calorimeter) measurements were performed to investigate the tetragonal‐monoclinic (t‐m) transition enthalpy of the compositionally homogeneous ZrO2‐X mol% CeO2 solid solution of X= 0, 4, 8, and 12. The transition enthalpy decreases linearly with an increase of CeO2 content. The m → t transition enthalpy on heating agreed well with the inverse t → m one obtained during cooling. With increasing X, the DSC peak broadens and the transition temperature distribution of each sample increases, while the thermal hysteresis is almost independent of X.
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U2 - 10.1111/j.1151-2916.1995.tb08642.x
DO - 10.1111/j.1151-2916.1995.tb08642.x
M3 - Article
AN - SCOPUS:35348854104
SN - 0002-7820
VL - 78
SP - 2225
EP - 2228
JO - Journal of the American Ceramic Society
JF - Journal of the American Ceramic Society
IS - 8
ER -