In this paper, the bending singularity at the apex of V-notch in an anisotropic thick plate is investigated. The Stroh-like formalism is used to model the anisotropy of the material. Based on the Ressiner-Mindlin plate theory and the eigenfunction expansion method, the characteristic equation for bending singularity order is derived and the order can be determined numerically. The numerical results show that the singularity orders strongly depend on the plate angle a. In addition, the singularity orders also depend on the principal orientation of the anisotropic material. The singularity orders for the case of are stronger than for that of. In the case of, to reduce the anisotropy is helpful to release the singularity at the notch tip. For the other case of, it is preferable to increase the anisotropy to reduce the singularity. The disappearance conditions of the bending singularity can be found based on the numerical results.