The dual roles of a V(iii) centre for substrate binding and oxygen atom abstraction; Nitrite reduction mediated by a V(iii) complex

Hung Ruei Pan; Zong Han Wu; Chin Ting Kuo; Han Jang Ou; Gene Hsiang Lee; Hua Fen Hsu

doi:10.1039/d0dt03274c

The dual roles of a V(iii) centre for substrate binding and oxygen atom abstraction; Nitrite reduction mediated by a V(iii) complex

Hung Ruei Pan
, Zong Han Wu
, Chin Ting Kuo
, Han Jang Ou
, Gene Hsiang Lee
, Hua Fen Hsu

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

A V(iii) complex bearing a tris(thiolato)phoshine derivative mediates the reduction of nitrite without the assistance of external protons or oxophilic substrates. The metal site plays dual roles for nitrite binding and deoxygenation. The reaction is monitored by spectroscopy combined with isotopic labeling experiments. The formed product, a {VNO}4 species, is isolated and characterized. This journal is

Original language	English
Pages (from-to)	14393-14396
Number of pages	4
Journal	Dalton Transactions
Volume	49
Issue number	41
DOIs	https://doi.org/10.1039/d0dt03274c
Publication status	Published - 2020 Nov 7

All Science Journal Classification (ASJC) codes

Inorganic Chemistry

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10.1039/d0dt03274c

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abstract = "A V(iii) complex bearing a tris(thiolato)phoshine derivative mediates the reduction of nitrite without the assistance of external protons or oxophilic substrates. The metal site plays dual roles for nitrite binding and deoxygenation. The reaction is monitored by spectroscopy combined with isotopic labeling experiments. The formed product, a \{VNO\}4 species, is isolated and characterized. This journal is ",

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AU - Wu, Zong Han

AU - Kuo, Chin Ting

AU - Ou, Han Jang

AU - Lee, Gene Hsiang

AU - Hsu, Hua Fen

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The dual roles of a V(iii) centre for substrate binding and oxygen atom abstraction; Nitrite reduction mediated by a V(iii) complex

Abstract

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