The nd1Δg (n=11-15) rydberg states of K2 studied by optical-optical double resonance spectroscopy and space charge limited diode ionization detector

J. T. Kim; C. C. Tsai; H. Wang; J. T. Bahns; W. C. Stwalley

doi:10.1006/jmsp.1995.1165

The nd¹Δg (n=11-15) rydberg states of K₂ studied by optical-optical double resonance spectroscopy and space charge limited diode ionization detector

J. T. Kim, C. C. Tsai, H. Wang, J. T. Bahns, W. C. Stwalley

Department of Physics

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

Five bound nd¹Δ_g (n = 11-15) electronic states have been investigated using optical-optical double resonance excitation followed by ionization detection using an ultrasensitive space charge limited diode, which detects ion signals (presumably K⁺₃ produced by associative ionization). The molecular constants and the Rydberg-Klein-Rees potential curves for these states have been generated. The dissociation energies, additional binding energies, and molecular constants due to the weakly bound Rydberg bonding δ_g orbitals are discussed.

Original language	English
Pages (from-to)	183-193
Number of pages	11
Journal	Journal of molecular spectroscopy
Volume	172
Issue number	1
DOIs	https://doi.org/10.1006/jmsp.1995.1165
Publication status	Published - 1995 Jul

All Science Journal Classification (ASJC) codes

Atomic and Molecular Physics, and Optics
Spectroscopy
Physical and Theoretical Chemistry

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10.1006/jmsp.1995.1165

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abstract = "Five bound nd1Δg (n = 11-15) electronic states have been investigated using optical-optical double resonance excitation followed by ionization detection using an ultrasensitive space charge limited diode, which detects ion signals (presumably K+3 produced by associative ionization). The molecular constants and the Rydberg-Klein-Rees potential curves for these states have been generated. The dissociation energies, additional binding energies, and molecular constants due to the weakly bound Rydberg bonding δg orbitals are discussed.",

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AU - Kim, J. T.

AU - Tsai, C. C.

AU - Wang, H.

AU - Bahns, J. T.

AU - Stwalley, W. C.

PY - 1995/7

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N2 - Five bound nd1Δg (n = 11-15) electronic states have been investigated using optical-optical double resonance excitation followed by ionization detection using an ultrasensitive space charge limited diode, which detects ion signals (presumably K+3 produced by associative ionization). The molecular constants and the Rydberg-Klein-Rees potential curves for these states have been generated. The dissociation energies, additional binding energies, and molecular constants due to the weakly bound Rydberg bonding δg orbitals are discussed.

AB - Five bound nd1Δg (n = 11-15) electronic states have been investigated using optical-optical double resonance excitation followed by ionization detection using an ultrasensitive space charge limited diode, which detects ion signals (presumably K+3 produced by associative ionization). The molecular constants and the Rydberg-Klein-Rees potential curves for these states have been generated. The dissociation energies, additional binding energies, and molecular constants due to the weakly bound Rydberg bonding δg orbitals are discussed.

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The nd¹Δg (n=11-15) rydberg states of K₂ studied by optical-optical double resonance spectroscopy and space charge limited diode ionization detector

Abstract

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