The radical reactions of imine radicals produced from the metal salts oxidation of 2-amino-1,4-benzoquinones

Po Yuan Lu, Kuang Po Chen, Che-Ping Chuang

Research output: Contribution to journalArticlepeer-review

4 Citations (Scopus)

Abstract

The metal salts mediated oxidative free radical reaction of 2-amino-1,4-benzoquinones is described. Imine radicals can be generated by the oxidation of 2-amino-1,4-benzoquinones with Mn(III) and Ag(II). The dimeric products 4 and 14 were formed via the intermolecular radical coupling reaction of the corresponding radical intermediates 5 and 15. In the presence of styrene, twistane 17 was afforded from 2-phenylamino-1,4-benzoquinone 1 via a radical annulation reaction of imine radical 5.

Original languageEnglish
Pages (from-to)7415-7421
Number of pages7
JournalTetrahedron
Volume65
Issue number36
DOIs
Publication statusPublished - 2009 Sep 5

All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

Fingerprint Dive into the research topics of 'The radical reactions of imine radicals produced from the metal salts oxidation of 2-amino-1,4-benzoquinones'. Together they form a unique fingerprint.

Cite this