The study of solvent additive effects in efficient polymer photovoltaics via impedance spectroscopy

En Ping Yao; Chun Chao Chen; Jing Gao; Yongsheng Liu; Qi Chen; Min Cai; Wei Chou Hsu; Ziruo Hong; Gang Li; Yang Yang

doi:10.1016/j.solmat.2014.05.049

The study of solvent additive effects in efficient polymer photovoltaics via impedance spectroscopy

En Ping Yao, Chun Chao Chen, Jing Gao, Yongsheng Liu, Qi Chen, Min Cai, Wei Chou Hsu, Ziruo Hong, Gang Li, Yang Yang

Research output: Contribution to journal › Article › peer-review

77 Citations (Scopus)

Abstract

1, 8-Diiodooctane (DIO) has been known for its role of improving the polymer morphology and enhancing performance of polymer bulk heterojunction (BHJ) solar cell. In this work, the impedance spectroscopy was used to investigate the interface of poly(4,8-bis-alkyloxybenzo(1,2-b:4,5-b′) dithiophene-2,6-diyl-alt- (alkyl thieno(3,4-b) thiophene-2-carboxylate)-2,6- diyl) (PBDTTT-C):PC₇₀BM in BHJ with DIO as additive. Based on our results, we were able to simulate the device into an equivalent circuit model, which allows us to conveniently analyze the organic/organic interfacial contact in the organic photovoltaic (OPV) device. Thus, we demonstrate that the impedance spectroscopy can an effective approach in characterizing the donor/acceptor interfaces, such that a direct correlation can be established between the morphology and the device performance of BHJ devices.

Original language	English
Pages (from-to)	20-26
Number of pages	7
Journal	Solar Energy Materials and Solar Cells
Volume	130
DOIs	https://doi.org/10.1016/j.solmat.2014.05.049
Publication status	Published - 2014 Nov

All Science Journal Classification (ASJC) codes

Electronic, Optical and Magnetic Materials
Renewable Energy, Sustainability and the Environment
Surfaces, Coatings and Films

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

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10.1016/j.solmat.2014.05.049

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@article{ee551894315c4a2eb142a60aeaba45a6,

title = "The study of solvent additive effects in efficient polymer photovoltaics via impedance spectroscopy",

abstract = "1, 8-Diiodooctane (DIO) has been known for its role of improving the polymer morphology and enhancing performance of polymer bulk heterojunction (BHJ) solar cell. In this work, the impedance spectroscopy was used to investigate the interface of poly(4,8-bis-alkyloxybenzo(1,2-b:4,5-b′) dithiophene-2,6-diyl-alt- (alkyl thieno(3,4-b) thiophene-2-carboxylate)-2,6- diyl) (PBDTTT-C):PC70BM in BHJ with DIO as additive. Based on our results, we were able to simulate the device into an equivalent circuit model, which allows us to conveniently analyze the organic/organic interfacial contact in the organic photovoltaic (OPV) device. Thus, we demonstrate that the impedance spectroscopy can an effective approach in characterizing the donor/acceptor interfaces, such that a direct correlation can be established between the morphology and the device performance of BHJ devices.",

author = "Yao, {En Ping} and Chen, {Chun Chao} and Jing Gao and Yongsheng Liu and Qi Chen and Min Cai and Hsu, {Wei Chou} and Ziruo Hong and Gang Li and Yang Yang",

year = "2014",

month = nov,

doi = "10.1016/j.solmat.2014.05.049",

language = "English",

volume = "130",

pages = "20--26",

journal = "Solar Energy Materials and Solar Cells",

issn = "0927-0248",

publisher = "Elsevier",

}

TY - JOUR

T1 - The study of solvent additive effects in efficient polymer photovoltaics via impedance spectroscopy

AU - Yao, En Ping

AU - Chen, Chun Chao

AU - Gao, Jing

AU - Liu, Yongsheng

AU - Chen, Qi

AU - Cai, Min

AU - Hsu, Wei Chou

AU - Hong, Ziruo

AU - Li, Gang

AU - Yang, Yang

PY - 2014/11

Y1 - 2014/11

N2 - 1, 8-Diiodooctane (DIO) has been known for its role of improving the polymer morphology and enhancing performance of polymer bulk heterojunction (BHJ) solar cell. In this work, the impedance spectroscopy was used to investigate the interface of poly(4,8-bis-alkyloxybenzo(1,2-b:4,5-b′) dithiophene-2,6-diyl-alt- (alkyl thieno(3,4-b) thiophene-2-carboxylate)-2,6- diyl) (PBDTTT-C):PC70BM in BHJ with DIO as additive. Based on our results, we were able to simulate the device into an equivalent circuit model, which allows us to conveniently analyze the organic/organic interfacial contact in the organic photovoltaic (OPV) device. Thus, we demonstrate that the impedance spectroscopy can an effective approach in characterizing the donor/acceptor interfaces, such that a direct correlation can be established between the morphology and the device performance of BHJ devices.

AB - 1, 8-Diiodooctane (DIO) has been known for its role of improving the polymer morphology and enhancing performance of polymer bulk heterojunction (BHJ) solar cell. In this work, the impedance spectroscopy was used to investigate the interface of poly(4,8-bis-alkyloxybenzo(1,2-b:4,5-b′) dithiophene-2,6-diyl-alt- (alkyl thieno(3,4-b) thiophene-2-carboxylate)-2,6- diyl) (PBDTTT-C):PC70BM in BHJ with DIO as additive. Based on our results, we were able to simulate the device into an equivalent circuit model, which allows us to conveniently analyze the organic/organic interfacial contact in the organic photovoltaic (OPV) device. Thus, we demonstrate that the impedance spectroscopy can an effective approach in characterizing the donor/acceptor interfaces, such that a direct correlation can be established between the morphology and the device performance of BHJ devices.

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U2 - 10.1016/j.solmat.2014.05.049

DO - 10.1016/j.solmat.2014.05.049

M3 - Article

AN - SCOPUS:84904325957

SN - 0927-0248

VL - 130

SP - 20

EP - 26

JO - Solar Energy Materials and Solar Cells

JF - Solar Energy Materials and Solar Cells

ER -

The study of solvent additive effects in efficient polymer photovoltaics via impedance spectroscopy

Abstract

All Science Journal Classification (ASJC) codes

UN SDGs

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