Abstract
A theoretical study of the tetraaminoethylene-diaminocarbene dissociation reaction shows that equilibrium is more readily attained for benzimidazol-2-ylidenes and doubly bridged imidazol-2-ylidenes. For imidazolin-2-ylidenes, the 'Wanzlick equilibrium' is less likely to occur due to the high reaction barrier. We demonstrate that the equilibrium reaction can be catalyzed by an electrophile.
| Original language | English |
|---|---|
| Pages (from-to) | 2617-2621 |
| Number of pages | 5 |
| Journal | Molecular Physics |
| Volume | 102 |
| Issue number | 23-24 |
| DOIs | |
| Publication status | Published - 2004 Dec 10 |
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All Science Journal Classification (ASJC) codes
- Biophysics
- Molecular Biology
- Condensed Matter Physics
- Physical and Theoretical Chemistry
Cite this
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Theoretical study of the Wanzlick equilibrium. / Cheng, Mu-Jeng; Lai, Chun Liang; Hu, Ching Han.
In: Molecular Physics, Vol. 102, No. 23-24, 10.12.2004, p. 2617-2621.Research output: Contribution to journal › Article
TY - JOUR
T1 - Theoretical study of the Wanzlick equilibrium
AU - Cheng, Mu-Jeng
AU - Lai, Chun Liang
AU - Hu, Ching Han
PY - 2004/12/10
Y1 - 2004/12/10
N2 - A theoretical study of the tetraaminoethylene-diaminocarbene dissociation reaction shows that equilibrium is more readily attained for benzimidazol-2-ylidenes and doubly bridged imidazol-2-ylidenes. For imidazolin-2-ylidenes, the 'Wanzlick equilibrium' is less likely to occur due to the high reaction barrier. We demonstrate that the equilibrium reaction can be catalyzed by an electrophile.
AB - A theoretical study of the tetraaminoethylene-diaminocarbene dissociation reaction shows that equilibrium is more readily attained for benzimidazol-2-ylidenes and doubly bridged imidazol-2-ylidenes. For imidazolin-2-ylidenes, the 'Wanzlick equilibrium' is less likely to occur due to the high reaction barrier. We demonstrate that the equilibrium reaction can be catalyzed by an electrophile.
UR - http://www.scopus.com/inward/record.url?scp=10944242275&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=10944242275&partnerID=8YFLogxK
U2 - 10.1080/00268970412331292911
DO - 10.1080/00268970412331292911
M3 - Article
AN - SCOPUS:10944242275
VL - 102
SP - 2617
EP - 2621
JO - Molecular Physics
JF - Molecular Physics
SN - 0026-8976
IS - 23-24
ER -