Thermal expansion behaviour of M′Ti2P3O12 (M′=Li, Na, K, Cs) and M″Ti4P6O24 (M″=Mg, Ca, Sr, Ba) compounds

C. Y. Huang; D. K. Agrawal; H. A. McKinstry

doi:10.1007/BF00349902

Thermal expansion behaviour of M′Ti₂P₃O₁₂ (M′=Li, Na, K, Cs) and M″Ti₄P₆O₂₄ (M″=Mg, Ca, Sr, Ba) compounds

C. Y. Huang, D. K. Agrawal, H. A. McKinstry

Department of Resources Engineering

Research output: Contribution to journal › Article › peer-review

32 Citations (Scopus)

Abstract

The [NZP] family has been attracting considerable attention because of its potential in thermal shock-resistant applications. The compounds M′Ti₂P₃O₁₂ (M″=Li, Na, K, Cs) and M″Ti₄P₆O₂₄ (M″=Mg, Ca, Sr, Ba) belong to this new family of low-expansion materials. The results of a systematic study undertaken to investigate the thermal expansion behaviour of these materials are reported. A correlation between the ionic size and lattice expansion was also attempted, and compounds possessing lowest bulk thermal and low anisotropy were identified.

Original language	English
Pages (from-to)	3509-3514
Number of pages	6
Journal	Journal of Materials Science
Volume	30
Issue number	13
DOIs	https://doi.org/10.1007/BF00349902
Publication status	Published - 1995 Jan 1

All Science Journal Classification (ASJC) codes

General Materials Science
Mechanics of Materials
Mechanical Engineering

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AU - McKinstry, H. A.

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AB - The [NZP] family has been attracting considerable attention because of its potential in thermal shock-resistant applications. The compounds M′Ti2P3O12 (M″=Li, Na, K, Cs) and M″Ti4P6O24 (M″=Mg, Ca, Sr, Ba) belong to this new family of low-expansion materials. The results of a systematic study undertaken to investigate the thermal expansion behaviour of these materials are reported. A correlation between the ionic size and lattice expansion was also attempted, and compounds possessing lowest bulk thermal and low anisotropy were identified.

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Thermal expansion behaviour of M′Ti₂P₃O₁₂ (M′=Li, Na, K, Cs) and M″Ti₄P₆O₂₄ (M″=Mg, Ca, Sr, Ba) compounds

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