Thermal stability of ordered mesoporous yttria-stabilized zirconia

I. Ming Hung; Kuan Zong Fung; De Tsai Hung; Min Hsiung Hon

doi:10.1016/j.jeurceramsoc.2007.09.044

Thermal stability of ordered mesoporous yttria-stabilized zirconia

I. Ming Hung, Kuan Zong Fung, De Tsai Hung, Min Hsiung Hon

Research output: Contribution to journal › Article › peer-review

13 Citations (Scopus)

Abstract

The hexagonal mesostructured nanocrystalline 16 mol% yttria-stabilized zirconia (8YSZ) formed by using a Pluronic triblock copolymer F127 as template is reported as a function of temperature. The characterization of the samples is achieved using wide-angle XRD diffraction, small-angle XRD diffraction, nitrogen adsorption-desorption, and transmission electron microscopy. The mesostructured 8YSZ calcined at 500 °C is found to be based upon a 2D periodic array of mesopores with diameter around 6.4 nm and the 8YSZ framework is composed of about 4.8 nm nanocrystallites. The sample has a BET surface area of 124 m²/g with a narrow pore size distribution. The ordered mesoporous structure remained even after calcination up to temperature of 600 °C grew out collapsed gradually when calcined above 700 °C owing to the fact that the crystallite size of 8YSZ larger than the inorganic pore-wall thickness.

Original language	English
Pages (from-to)	1161-1167
Number of pages	7
Journal	Journal of the European Ceramic Society
Volume	28
Issue number	6
DOIs	https://doi.org/10.1016/j.jeurceramsoc.2007.09.044
Publication status	Published - 2008

All Science Journal Classification (ASJC) codes

Ceramics and Composites
Materials Chemistry

Access to Document

10.1016/j.jeurceramsoc.2007.09.044

Cite this

@article{eebce5ecf8254ba881847138f1c882dc,

title = "Thermal stability of ordered mesoporous yttria-stabilized zirconia",

abstract = "The hexagonal mesostructured nanocrystalline 16 mol% yttria-stabilized zirconia (8YSZ) formed by using a Pluronic triblock copolymer F127 as template is reported as a function of temperature. The characterization of the samples is achieved using wide-angle XRD diffraction, small-angle XRD diffraction, nitrogen adsorption-desorption, and transmission electron microscopy. The mesostructured 8YSZ calcined at 500 °C is found to be based upon a 2D periodic array of mesopores with diameter around 6.4 nm and the 8YSZ framework is composed of about 4.8 nm nanocrystallites. The sample has a BET surface area of 124 m2/g with a narrow pore size distribution. The ordered mesoporous structure remained even after calcination up to temperature of 600 °C grew out collapsed gradually when calcined above 700 °C owing to the fact that the crystallite size of 8YSZ larger than the inorganic pore-wall thickness.",

author = "Hung, {I. Ming} and Fung, {Kuan Zong} and Hung, {De Tsai} and Hon, {Min Hsiung}",

note = "Funding Information: This work is supported by the National Science Council of Taiwan under grant No. NSC-94-2120-M-006-002 and NSC95-2221-E-006-200. Copyright: Copyright 2008 Elsevier B.V., All rights reserved.",

year = "2008",

doi = "10.1016/j.jeurceramsoc.2007.09.044",

language = "English",

volume = "28",

pages = "1161--1167",

journal = "Journal of the European Ceramic Society",

issn = "0955-2219",

publisher = "Elsevier BV",

number = "6",

}

TY - JOUR

T1 - Thermal stability of ordered mesoporous yttria-stabilized zirconia

AU - Hung, I. Ming

AU - Fung, Kuan Zong

AU - Hung, De Tsai

AU - Hon, Min Hsiung

N1 - Funding Information: This work is supported by the National Science Council of Taiwan under grant No. NSC-94-2120-M-006-002 and NSC95-2221-E-006-200. Copyright: Copyright 2008 Elsevier B.V., All rights reserved.

PY - 2008

Y1 - 2008

N2 - The hexagonal mesostructured nanocrystalline 16 mol% yttria-stabilized zirconia (8YSZ) formed by using a Pluronic triblock copolymer F127 as template is reported as a function of temperature. The characterization of the samples is achieved using wide-angle XRD diffraction, small-angle XRD diffraction, nitrogen adsorption-desorption, and transmission electron microscopy. The mesostructured 8YSZ calcined at 500 °C is found to be based upon a 2D periodic array of mesopores with diameter around 6.4 nm and the 8YSZ framework is composed of about 4.8 nm nanocrystallites. The sample has a BET surface area of 124 m2/g with a narrow pore size distribution. The ordered mesoporous structure remained even after calcination up to temperature of 600 °C grew out collapsed gradually when calcined above 700 °C owing to the fact that the crystallite size of 8YSZ larger than the inorganic pore-wall thickness.

AB - The hexagonal mesostructured nanocrystalline 16 mol% yttria-stabilized zirconia (8YSZ) formed by using a Pluronic triblock copolymer F127 as template is reported as a function of temperature. The characterization of the samples is achieved using wide-angle XRD diffraction, small-angle XRD diffraction, nitrogen adsorption-desorption, and transmission electron microscopy. The mesostructured 8YSZ calcined at 500 °C is found to be based upon a 2D periodic array of mesopores with diameter around 6.4 nm and the 8YSZ framework is composed of about 4.8 nm nanocrystallites. The sample has a BET surface area of 124 m2/g with a narrow pore size distribution. The ordered mesoporous structure remained even after calcination up to temperature of 600 °C grew out collapsed gradually when calcined above 700 °C owing to the fact that the crystallite size of 8YSZ larger than the inorganic pore-wall thickness.

UR - http://www.scopus.com/inward/record.url?scp=38849209279&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=38849209279&partnerID=8YFLogxK

U2 - 10.1016/j.jeurceramsoc.2007.09.044

DO - 10.1016/j.jeurceramsoc.2007.09.044

M3 - Article

AN - SCOPUS:38849209279

SN - 0955-2219

VL - 28

SP - 1161

EP - 1167

JO - Journal of the European Ceramic Society

JF - Journal of the European Ceramic Society

IS - 6

ER -

Thermal stability of ordered mesoporous yttria-stabilized zirconia

Abstract

All Science Journal Classification (ASJC) codes

Access to Document

Other files and links

Fingerprint

Cite this