Universal ferroelectric switching dynamics of vinylidene fluoride-trifluoroethylene copolymer films

Wei Jin Hu; Deng Ming Juo; Lu You; Junling Wang; Yi Chun Chen; Ying Hao Chu; Tom Wu

doi:10.1038/srep04772

Universal ferroelectric switching dynamics of vinylidene fluoride-trifluoroethylene copolymer films

Wei Jin Hu, Deng Ming Juo, Lu You, Junling Wang, Yi Chun Chen, Ying Hao Chu, Tom Wu

Department of Physics

Research output: Contribution to journal › Article › peer-review

139 Citations (Scopus)

Abstract

In this work, switching dynamics of poly(vinylidene fluoride- trifluoroethylene) [P(VDF-TrFE)] copolymer films are investigated over unprecedentedly wide ranges of temperature and electric field. Remarkably, domain switching of copolymer films obeys well the classical domain nucleation and growth model although the origin of ferroelectricity in organic ferroelectric materials inherently differs from the inorganic counterparts. A lower coercivity limit of 50â €...MV/m and 180° domain wall energy of 60â €...mJ/m 2 are determined for P(VDF-TrFE) films. Furthermore, we discover in copolymer films an anomalous temperature-dependent crossover behavior between two power-law scaling regimes of frequency-dependent coercivity, which is attributed to the transition between flow and creep motions of domain walls. Our observations shed new light on the switching dynamics of semi-crystalline ferroelectric polymers, and such understandings are critical for realizing their reliable applications.

Original language	English
Article number	4772
Journal	Scientific reports
Volume	4
DOIs	https://doi.org/10.1038/srep04772
Publication status	Published - 2014 Apr 24

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title = "Universal ferroelectric switching dynamics of vinylidene fluoride-trifluoroethylene copolymer films",

abstract = "In this work, switching dynamics of poly(vinylidene fluoride- trifluoroethylene) [P(VDF-TrFE)] copolymer films are investigated over unprecedentedly wide ranges of temperature and electric field. Remarkably, domain switching of copolymer films obeys well the classical domain nucleation and growth model although the origin of ferroelectricity in organic ferroelectric materials inherently differs from the inorganic counterparts. A lower coercivity limit of 50{\^a} €...MV/m and 180° domain wall energy of 60{\^a} €...mJ/m 2 are determined for P(VDF-TrFE) films. Furthermore, we discover in copolymer films an anomalous temperature-dependent crossover behavior between two power-law scaling regimes of frequency-dependent coercivity, which is attributed to the transition between flow and creep motions of domain walls. Our observations shed new light on the switching dynamics of semi-crystalline ferroelectric polymers, and such understandings are critical for realizing their reliable applications.",

author = "Hu, {Wei Jin} and Juo, {Deng Ming} and Lu You and Junling Wang and Chen, {Yi Chun} and Chu, {Ying Hao} and Tom Wu",

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doi = "10.1038/srep04772",

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T1 - Universal ferroelectric switching dynamics of vinylidene fluoride-trifluoroethylene copolymer films

AU - Hu, Wei Jin

AU - Juo, Deng Ming

AU - You, Lu

AU - Wang, Junling

AU - Chen, Yi Chun

AU - Chu, Ying Hao

AU - Wu, Tom

PY - 2014/4/24

Y1 - 2014/4/24

N2 - In this work, switching dynamics of poly(vinylidene fluoride- trifluoroethylene) [P(VDF-TrFE)] copolymer films are investigated over unprecedentedly wide ranges of temperature and electric field. Remarkably, domain switching of copolymer films obeys well the classical domain nucleation and growth model although the origin of ferroelectricity in organic ferroelectric materials inherently differs from the inorganic counterparts. A lower coercivity limit of 50â €...MV/m and 180° domain wall energy of 60â €...mJ/m 2 are determined for P(VDF-TrFE) films. Furthermore, we discover in copolymer films an anomalous temperature-dependent crossover behavior between two power-law scaling regimes of frequency-dependent coercivity, which is attributed to the transition between flow and creep motions of domain walls. Our observations shed new light on the switching dynamics of semi-crystalline ferroelectric polymers, and such understandings are critical for realizing their reliable applications.

AB - In this work, switching dynamics of poly(vinylidene fluoride- trifluoroethylene) [P(VDF-TrFE)] copolymer films are investigated over unprecedentedly wide ranges of temperature and electric field. Remarkably, domain switching of copolymer films obeys well the classical domain nucleation and growth model although the origin of ferroelectricity in organic ferroelectric materials inherently differs from the inorganic counterparts. A lower coercivity limit of 50â €...MV/m and 180° domain wall energy of 60â €...mJ/m 2 are determined for P(VDF-TrFE) films. Furthermore, we discover in copolymer films an anomalous temperature-dependent crossover behavior between two power-law scaling regimes of frequency-dependent coercivity, which is attributed to the transition between flow and creep motions of domain walls. Our observations shed new light on the switching dynamics of semi-crystalline ferroelectric polymers, and such understandings are critical for realizing their reliable applications.

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Universal ferroelectric switching dynamics of vinylidene fluoride-trifluoroethylene copolymer films

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