Variation in the electron count and ground state of [Mn12O 12(O2CR)16(H2O)4] (R = Me or Ph) by metal substitution and redox changes: Preparation and properties of [Mn8Fe4O12(O2CMe) 16(H2O)4]·4H2O· 2MeCO2H and...

Ann R. Schake; Hui Lien Tsai; Nadine De Vries; Robert J. Webb; Kirsten Folting; David N. Hendrickson; George Christou

doi:10.1039/C39920000181

Variation in the electron count and ground state of [Mn₁₂O ₁₂(O₂CR)₁₆(H₂O)₄] (R = Me or Ph) by metal substitution and redox changes: Preparation and properties of [Mn₈Fe₄O₁₂(O₂CMe) ₁₆(H₂O)₄]·4H₂O· 2MeCO₂H and...

Ann R. Schake, Hui Lien Tsai, Nadine De Vries, Robert J. Webb, Kirsten Folting, David N. Hendrickson, George Christou

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

55 Citations (Scopus)

Abstract

Title full: Variation in the electron count and ground state of [Mn₁₂O ₁₂(O₂CR)₁₆(H₂O)₄] (R = Me or Ph) by metal substitution and redox changes: Preparation and properties of [Mn₈Fe₄O₁₂(O₂CMe) ₁₆(H₂O)₄]·4H₂O· 2MeCO₂H and [NPrⁿ₄] [Mn₁₂O ₁₂(O₂CPh)₁₆(H₂O)₄] ·H₂O. As a means of varying the electron count of complexes [Mn ₁₂O₁₂(O₂CR)₁₆(H₂O) ₄](1; R = Me or Ph), the aggregates [Mn₈Fe ₄O₁₂(O₂CMe)₁₆(H₂O) ₄] 2 and [NPrⁿ₄] [Mn₁₂O ₁₂(O₂CPh)₁₆(H₂O)₄] 3 have been prepared; magnetochemical measurements confirm that the unusual of properties 1 can be significantly altered by 'conversion' to 2 and 3.

Original language	English
Pages (from-to)	181-183
Number of pages	3
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	2
DOIs	https://doi.org/10.1039/C39920000181
Publication status	Published - 1992

All Science Journal Classification (ASJC) codes

Molecular Medicine

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10.1039/C39920000181

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Dive into the research topics of 'Variation in the electron count and ground state of [Mn₁₂O ₁₂(O₂CR)₁₆(H₂O)₄] (R = Me or Ph) by metal substitution and redox changes: Preparation and properties of [Mn₈Fe₄O₁₂(O₂CMe) ₁₆(H₂O)₄]·4H₂O· 2MeCO₂H and...'. Together they form a unique fingerprint.

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Schake, A. R., Tsai, H. L., De Vries, N., Webb, R. J., Folting, K., Hendrickson, D. N., & Christou, G. (1992). Variation in the electron count and ground state of [Mn₁₂O ₁₂(O₂CR)₁₆(H₂O)₄] (R = Me or Ph) by metal substitution and redox changes: Preparation and properties of [Mn₈Fe₄O₁₂(O₂CMe) ₁₆(H₂O)₄]·4H₂O· 2MeCO₂H and... Journal of the Chemical Society, Chemical Communications, (2), 181-183. https://doi.org/10.1039/C39920000181

@article{2637a95deba14e7fa9fd5e5e2d3d4be9,

title = "Variation in the electron count and ground state of [Mn12O 12(O2CR)16(H2O)4] (R = Me or Ph) by metal substitution and redox changes: Preparation and properties of [Mn8Fe4O12(O2CMe) 16(H2O)4]·4H2O· 2MeCO2H and...",

abstract = "Title full: Variation in the electron count and ground state of [Mn12O 12(O2CR)16(H2O)4] (R = Me or Ph) by metal substitution and redox changes: Preparation and properties of [Mn8Fe4O12(O2CMe) 16(H2O)4]·4H2O· 2MeCO2H and [NPrn4] [Mn12O 12(O2CPh)16(H2O)4] ·H2O. As a means of varying the electron count of complexes [Mn 12O12(O2CR)16(H2O) 4](1; R = Me or Ph), the aggregates [Mn8Fe 4O12(O2CMe)16(H2O) 4] 2 and [NPrn4] [Mn12O 12(O2CPh)16(H2O)4] 3 have been prepared; magnetochemical measurements confirm that the unusual of properties 1 can be significantly altered by 'conversion' to 2 and 3.",

author = "Schake, {Ann R.} and Tsai, {Hui Lien} and {De Vries}, Nadine and Webb, {Robert J.} and Kirsten Folting and Hendrickson, {David N.} and George Christou",

year = "1992",

doi = "10.1039/C39920000181",

language = "English",

pages = "181--183",

journal = "Journal of the Chemical Society, Chemical Communications",

issn = "0022-4936",

publisher = "Royal Society of Chemistry",

number = "2",

}

Schake, AR, Tsai, HL, De Vries, N, Webb, RJ, Folting, K, Hendrickson, DN & Christou, G 1992, 'Variation in the electron count and ground state of [Mn₁₂O ₁₂(O₂CR)₁₆(H₂O)₄] (R = Me or Ph) by metal substitution and redox changes: Preparation and properties of [Mn₈Fe₄O₁₂(O₂CMe) ₁₆(H₂O)₄]·4H₂O· 2MeCO₂H and...', Journal of the Chemical Society, Chemical Communications, no. 2, pp. 181-183. https://doi.org/10.1039/C39920000181

Variation in the electron count and ground state of [Mn₁₂O ₁₂(O₂CR)₁₆(H₂O)₄] (R = Me or Ph) by metal substitution and redox changes: Preparation and properties of [Mn₈Fe₄O₁₂(O₂CMe) ₁₆(H₂O)₄]·4H₂O· 2MeCO₂H and... / Schake, Ann R.; Tsai, Hui Lien; De Vries, Nadine et al.
In: Journal of the Chemical Society, Chemical Communications, No. 2, 1992, p. 181-183.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Variation in the electron count and ground state of [Mn12O 12(O2CR)16(H2O)4] (R = Me or Ph) by metal substitution and redox changes

T2 - Preparation and properties of [Mn8Fe4O12(O2CMe) 16(H2O)4]·4H2O· 2MeCO2H and...

AU - Schake, Ann R.

AU - Tsai, Hui Lien

AU - De Vries, Nadine

AU - Webb, Robert J.

AU - Folting, Kirsten

AU - Hendrickson, David N.

AU - Christou, George

PY - 1992

Y1 - 1992

N2 - Title full: Variation in the electron count and ground state of [Mn12O 12(O2CR)16(H2O)4] (R = Me or Ph) by metal substitution and redox changes: Preparation and properties of [Mn8Fe4O12(O2CMe) 16(H2O)4]·4H2O· 2MeCO2H and [NPrn4] [Mn12O 12(O2CPh)16(H2O)4] ·H2O. As a means of varying the electron count of complexes [Mn 12O12(O2CR)16(H2O) 4](1; R = Me or Ph), the aggregates [Mn8Fe 4O12(O2CMe)16(H2O) 4] 2 and [NPrn4] [Mn12O 12(O2CPh)16(H2O)4] 3 have been prepared; magnetochemical measurements confirm that the unusual of properties 1 can be significantly altered by 'conversion' to 2 and 3.

AB - Title full: Variation in the electron count and ground state of [Mn12O 12(O2CR)16(H2O)4] (R = Me or Ph) by metal substitution and redox changes: Preparation and properties of [Mn8Fe4O12(O2CMe) 16(H2O)4]·4H2O· 2MeCO2H and [NPrn4] [Mn12O 12(O2CPh)16(H2O)4] ·H2O. As a means of varying the electron count of complexes [Mn 12O12(O2CR)16(H2O) 4](1; R = Me or Ph), the aggregates [Mn8Fe 4O12(O2CMe)16(H2O) 4] 2 and [NPrn4] [Mn12O 12(O2CPh)16(H2O)4] 3 have been prepared; magnetochemical measurements confirm that the unusual of properties 1 can be significantly altered by 'conversion' to 2 and 3.

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U2 - 10.1039/C39920000181

DO - 10.1039/C39920000181

M3 - Article

AN - SCOPUS:10444249668

SN - 0022-4936

SP - 181

EP - 183

JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

IS - 2

ER -

Schake AR, Tsai HL, De Vries N, Webb RJ, Folting K, Hendrickson DN et al. Variation in the electron count and ground state of [Mn₁₂O ₁₂(O₂CR)₁₆(H₂O)₄] (R = Me or Ph) by metal substitution and redox changes: Preparation and properties of [Mn₈Fe₄O₁₂(O₂CMe) ₁₆(H₂O)₄]·4H₂O· 2MeCO₂H and... Journal of the Chemical Society, Chemical Communications. 1992;(2):181-183. doi: 10.1039/C39920000181