W/Zr mixed oxide supported on mesoporous silica as catalyst for n-pentane isomerization

Tao Li; She Tin Wong; Man Chien Chao; Hong Ping Lin; Chung Yuan Mou; Soofin Cheng

doi:10.1016/S0167-2991(03)80447-0

W/Zr mixed oxide supported on mesoporous silica as catalyst for n-pentane isomerization

Tao Li, She Tin Wong, Man Chien Chao, Hong Ping Lin, Chung Yuan Mou, Soofin Cheng

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

WO₃/ZrO₂ mixed oxides supported on various porous silica were prepared. For the mesoporous silica, SBA-15 was found to retain the crystalline structure better than MCM-41 after loading W/Zr mixed oxides. Tungstated zirconia is mainly dispersed into the mesoporous channels of SBA-15, which causes the dramatical decrease in the surface area and pore volume. All the mesoporous siliceous materials supported solid acid samples showed strong acidity. The SBA-15 supported WO₃/ZrO₂ materials promoted with Pt were highly efficient in catalyzing the isomerization of n-pentane with a high selectivity of isopentane. SBA-15 with 1 %Pt/20%WO₃/ 40%ZrO₂ gave the highest catalytic activity.

Original language	English
Pages (from-to)	569-572
Number of pages	4
Journal	Studies in Surface Science and Catalysis
Volume	146
DOIs	https://doi.org/10.1016/S0167-2991(03)80447-0
Publication status	Published - 2003 Jan 1

All Science Journal Classification (ASJC) codes

Catalysis
Condensed Matter Physics
Physical and Theoretical Chemistry
Surfaces, Coatings and Films
Materials Chemistry

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10.1016/S0167-2991(03)80447-0

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title = "W/Zr mixed oxide supported on mesoporous silica as catalyst for n-pentane isomerization",

abstract = "WO3/ZrO2 mixed oxides supported on various porous silica were prepared. For the mesoporous silica, SBA-15 was found to retain the crystalline structure better than MCM-41 after loading W/Zr mixed oxides. Tungstated zirconia is mainly dispersed into the mesoporous channels of SBA-15, which causes the dramatical decrease in the surface area and pore volume. All the mesoporous siliceous materials supported solid acid samples showed strong acidity. The SBA-15 supported WO3/ZrO2 materials promoted with Pt were highly efficient in catalyzing the isomerization of n-pentane with a high selectivity of isopentane. SBA-15 with 1 %Pt/20%WO3/ 40%ZrO2 gave the highest catalytic activity.",

author = "Tao Li and Wong, {She Tin} and Chao, {Man Chien} and Lin, {Hong Ping} and Mou, {Chung Yuan} and Soofin Cheng",

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T1 - W/Zr mixed oxide supported on mesoporous silica as catalyst for n-pentane isomerization

AU - Li, Tao

AU - Wong, She Tin

AU - Chao, Man Chien

AU - Lin, Hong Ping

AU - Mou, Chung Yuan

AU - Cheng, Soofin

PY - 2003/1/1

Y1 - 2003/1/1

N2 - WO3/ZrO2 mixed oxides supported on various porous silica were prepared. For the mesoporous silica, SBA-15 was found to retain the crystalline structure better than MCM-41 after loading W/Zr mixed oxides. Tungstated zirconia is mainly dispersed into the mesoporous channels of SBA-15, which causes the dramatical decrease in the surface area and pore volume. All the mesoporous siliceous materials supported solid acid samples showed strong acidity. The SBA-15 supported WO3/ZrO2 materials promoted with Pt were highly efficient in catalyzing the isomerization of n-pentane with a high selectivity of isopentane. SBA-15 with 1 %Pt/20%WO3/ 40%ZrO2 gave the highest catalytic activity.

AB - WO3/ZrO2 mixed oxides supported on various porous silica were prepared. For the mesoporous silica, SBA-15 was found to retain the crystalline structure better than MCM-41 after loading W/Zr mixed oxides. Tungstated zirconia is mainly dispersed into the mesoporous channels of SBA-15, which causes the dramatical decrease in the surface area and pore volume. All the mesoporous siliceous materials supported solid acid samples showed strong acidity. The SBA-15 supported WO3/ZrO2 materials promoted with Pt were highly efficient in catalyzing the isomerization of n-pentane with a high selectivity of isopentane. SBA-15 with 1 %Pt/20%WO3/ 40%ZrO2 gave the highest catalytic activity.

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EP - 572

JO - Studies in Surface Science and Catalysis

JF - Studies in Surface Science and Catalysis

ER -

W/Zr mixed oxide supported on mesoporous silica as catalyst for n-pentane isomerization

Abstract

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