X-ray absorption near-edge spectroscopy study of photoluminescent Ca2.955Sc2-xAlxSi3O12:Ce3+ green phosphors

Yun Fang Wu; Jau Wern Chiou; Yung Tang Nien; Chen Lin Yeh; In Gann Chen; Jyh Fu Lee

doi:10.1016/j.ceramint.2014.11.149

X-ray absorption near-edge spectroscopy study of photoluminescent Ca_2.955Sc_2-xAl_xSi₃O₁₂:Ce³⁺ green phosphors

Yun Fang Wu, Jau Wern Chiou, Yung Tang Nien, Chen Lin Yeh, In Gann Chen, Jyh Fu Lee

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

Al³⁺ co-doped Ca_2.955Sc₂Si₃O₁₂:Ce³⁺ green phosphors were systematically investigated using X-ray absorption near-edge spectroscopy (XANES) to understand the influence of Al³⁺ incorporation on photoluminescence behavior. XANES analysis was used to confirm the doping site of Al atoms in the Ca_2.955Sc₂Si₃O₁₂:Ce³⁺ host, the valence state of Ce atoms, the symmetry around Ca and Ce atoms, and the bonding modes of oxygen atoms with cation atoms in the as-prepared Ca_2.955Sc_2-xAl_xSi₃O₁₂:Ce³⁺ (CSAS:Ce). XANES results indicate that Al³⁺ occupies the Sc³⁺ sites and stabilizes the crystal structure of the host material. Furthermore, Al³⁺ can effectively inhibit the oxidization of Ce³⁺ to Ce⁴⁺, which enhances the photoluminescence of CSAS:Ce green phosphors.

Original language	English
Pages (from-to)	4538-4543
Number of pages	6
Journal	Ceramics International
Volume	41
Issue number	3
DOIs	https://doi.org/10.1016/j.ceramint.2014.11.149
Publication status	Published - 2015 Apr 1

All Science Journal Classification (ASJC) codes

Electronic, Optical and Magnetic Materials
Ceramics and Composites
Process Chemistry and Technology
Surfaces, Coatings and Films
Materials Chemistry

Access to Document

10.1016/j.ceramint.2014.11.149

Cite this

@article{7414b8a11f6d461982160c82f1190b08,

title = "X-ray absorption near-edge spectroscopy study of photoluminescent Ca2.955Sc2-xAlxSi3O12:Ce3+ green phosphors",

abstract = "Al3+ co-doped Ca2.955Sc2Si3O12:Ce3+ green phosphors were systematically investigated using X-ray absorption near-edge spectroscopy (XANES) to understand the influence of Al3+ incorporation on photoluminescence behavior. XANES analysis was used to confirm the doping site of Al atoms in the Ca2.955Sc2Si3O12:Ce3+ host, the valence state of Ce atoms, the symmetry around Ca and Ce atoms, and the bonding modes of oxygen atoms with cation atoms in the as-prepared Ca2.955Sc2-xAlxSi3O12:Ce3+ (CSAS:Ce). XANES results indicate that Al3+ occupies the Sc3+ sites and stabilizes the crystal structure of the host material. Furthermore, Al3+ can effectively inhibit the oxidization of Ce3+ to Ce4+, which enhances the photoluminescence of CSAS:Ce green phosphors.",

author = "Wu, {Yun Fang} and Chiou, {Jau Wern} and Nien, {Yung Tang} and Yeh, {Chen Lin} and Chen, {In Gann} and Lee, {Jyh Fu}",

note = "Funding Information: The authors would like to thank the National Science Council ( NSC 102-2221-E-150-071- ) and the Ministry of Science and Technology ( MOST 103-2112-M-390-001 and MOST 103-2120-M-006-004-CC1 ) for their financial support. Publisher Copyright: {\textcopyright} 2014 Elsevier Ltd and Techna Group S.r.l.",

year = "2015",

month = apr,

day = "1",

doi = "10.1016/j.ceramint.2014.11.149",

language = "English",

volume = "41",

pages = "4538--4543",

journal = "Ceramics International",

issn = "0272-8842",

publisher = "Elsevier Limited",

number = "3",

}

TY - JOUR

T1 - X-ray absorption near-edge spectroscopy study of photoluminescent Ca2.955Sc2-xAlxSi3O12:Ce3+ green phosphors

AU - Wu, Yun Fang

AU - Chiou, Jau Wern

AU - Nien, Yung Tang

AU - Yeh, Chen Lin

AU - Chen, In Gann

AU - Lee, Jyh Fu

N1 - Funding Information: The authors would like to thank the National Science Council ( NSC 102-2221-E-150-071- ) and the Ministry of Science and Technology ( MOST 103-2112-M-390-001 and MOST 103-2120-M-006-004-CC1 ) for their financial support. Publisher Copyright: © 2014 Elsevier Ltd and Techna Group S.r.l.

PY - 2015/4/1

Y1 - 2015/4/1

N2 - Al3+ co-doped Ca2.955Sc2Si3O12:Ce3+ green phosphors were systematically investigated using X-ray absorption near-edge spectroscopy (XANES) to understand the influence of Al3+ incorporation on photoluminescence behavior. XANES analysis was used to confirm the doping site of Al atoms in the Ca2.955Sc2Si3O12:Ce3+ host, the valence state of Ce atoms, the symmetry around Ca and Ce atoms, and the bonding modes of oxygen atoms with cation atoms in the as-prepared Ca2.955Sc2-xAlxSi3O12:Ce3+ (CSAS:Ce). XANES results indicate that Al3+ occupies the Sc3+ sites and stabilizes the crystal structure of the host material. Furthermore, Al3+ can effectively inhibit the oxidization of Ce3+ to Ce4+, which enhances the photoluminescence of CSAS:Ce green phosphors.

AB - Al3+ co-doped Ca2.955Sc2Si3O12:Ce3+ green phosphors were systematically investigated using X-ray absorption near-edge spectroscopy (XANES) to understand the influence of Al3+ incorporation on photoluminescence behavior. XANES analysis was used to confirm the doping site of Al atoms in the Ca2.955Sc2Si3O12:Ce3+ host, the valence state of Ce atoms, the symmetry around Ca and Ce atoms, and the bonding modes of oxygen atoms with cation atoms in the as-prepared Ca2.955Sc2-xAlxSi3O12:Ce3+ (CSAS:Ce). XANES results indicate that Al3+ occupies the Sc3+ sites and stabilizes the crystal structure of the host material. Furthermore, Al3+ can effectively inhibit the oxidization of Ce3+ to Ce4+, which enhances the photoluminescence of CSAS:Ce green phosphors.

UR - http://www.scopus.com/inward/record.url?scp=84922843047&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84922843047&partnerID=8YFLogxK

U2 - 10.1016/j.ceramint.2014.11.149

DO - 10.1016/j.ceramint.2014.11.149

M3 - Article

AN - SCOPUS:84922843047

SN - 0272-8842

VL - 41

SP - 4538

EP - 4543

JO - Ceramics International

JF - Ceramics International

IS - 3

ER -

X-ray absorption near-edge spectroscopy study of photoluminescent Ca_2.955Sc_2-xAl_xSi₃O₁₂:Ce³⁺ green phosphors

Abstract

All Science Journal Classification (ASJC) codes

Access to Document

Other files and links

Fingerprint

Cite this