1,3,4,6,7,9-Hexamethylbenzo[1,2-c:3,4-c′:5,6-c′′] trithiophene: A twisted heteroarene

Yao-Ting Wu, Chia Cheng Tai, Wei Chih Lin, Kim K. Baldridge

研究成果: Article

5 引文 斯高帕斯(Scopus)

摘要

1,3,4,6,7,9-Hexamethylbenzo[1,2-c:3,4-c′:5,6-c″]trithiophene (C-Me) was prepared by palladium-catalyzed methylations of the corresponding hexabromide C-Br. The twisted structure of C-Me has been confirmed by X-ray crystal analysis. The physical properties of twisted C-Me and planar benzo[1,2-c:3,4-c′:5,6-c″]trithiophene (C-H) were studied and compared. Crystal structures are compared to computational structures determined using density functional theory, with both the M06-2X and B3PW91 functionals.

原文English
頁(從 - 到)2748-2755
頁數8
期刊Organic and Biomolecular Chemistry
7
發行號13
DOIs
出版狀態Published - 2009 六月 26

    指紋

All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry

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