A composite film prepared from titanium carbide Ti3C2Tx (MXene) and gold nanoparticles for voltammetric determination of uric acid and folic acid

Satheeshkumar Elumalai, Veerappan Mani, Nithiya Jeromiyas, Vinoth Kumar Ponnusamy, Masahiro Yoshimura

研究成果: Article

摘要

In this study, a solution-processing based galvanic deposition approach is described for in-situ deposition of gold nanoparticles (AuNP) on delaminated titanium Ti3C2Tx nanosheets under ultrasonication. The nanocomposite (AuNP@Ti3C2Tx) was placed on a glassy carbon electrode (GCE) and then applied to electrochemically with label-free, and simultaneously sense uric acid (UA), and folic acid (FA) at physiological pH. The modified GCE has attractive figures of merit: (i) The working potentials for UA and AA are well separated (+0.35 V and 0.70 V vs. Ag|AgCl); (ii) wide linear responses (from 0.03–1520 μM for UA and from 0.02–3580 μM for FA; (iii) good electrochemical sensitivities for both UA and FA (0.53 and 0.494 μAμM−1.cm−2, respectively), and (iv) detection limits of 11.5 nM (UA) and 6.20 nM (FA). The electrode exhibited good repeatability (RSD = 4.4%), acceptable reproducibility (RSD = 4.1%), and excellent stability (91.8% over one-month storage). The method was applied to analyze spiked serum samples, and modified GCE is shown appreciable recoveries (97.1–98.8% and 96.8–98.0% for UA, and FA, respectively). [Figure not available: see fulltext.].

原文English
文章編號33
期刊Microchimica Acta
187
發行號1
DOIs
出版狀態Published - 2020 一月 1

指紋

Composite films
Uric Acid
Folic Acid
Gold
Nanoparticles
Glassy carbon
Electrodes
Nanosheets
Titanium
titanium carbide
Labels
Nanocomposites
Recovery
Processing

All Science Journal Classification (ASJC) codes

  • Analytical Chemistry

引用此文

Elumalai, Satheeshkumar ; Mani, Veerappan ; Jeromiyas, Nithiya ; Ponnusamy, Vinoth Kumar ; Yoshimura, Masahiro. / A composite film prepared from titanium carbide Ti3C2Tx (MXene) and gold nanoparticles for voltammetric determination of uric acid and folic acid. 於: Microchimica Acta. 2020 ; 卷 187, 編號 1.
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A composite film prepared from titanium carbide Ti3C2Tx (MXene) and gold nanoparticles for voltammetric determination of uric acid and folic acid. / Elumalai, Satheeshkumar; Mani, Veerappan; Jeromiyas, Nithiya; Ponnusamy, Vinoth Kumar; Yoshimura, Masahiro.

於: Microchimica Acta, 卷 187, 編號 1, 33, 01.01.2020.

研究成果: Article

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AU - Elumalai, Satheeshkumar

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AU - Jeromiyas, Nithiya

AU - Ponnusamy, Vinoth Kumar

AU - Yoshimura, Masahiro

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N2 - In this study, a solution-processing based galvanic deposition approach is described for in-situ deposition of gold nanoparticles (AuNP) on delaminated titanium Ti3C2Tx nanosheets under ultrasonication. The nanocomposite (AuNP@Ti3C2Tx) was placed on a glassy carbon electrode (GCE) and then applied to electrochemically with label-free, and simultaneously sense uric acid (UA), and folic acid (FA) at physiological pH. The modified GCE has attractive figures of merit: (i) The working potentials for UA and AA are well separated (+0.35 V and 0.70 V vs. Ag|AgCl); (ii) wide linear responses (from 0.03–1520 μM for UA and from 0.02–3580 μM for FA; (iii) good electrochemical sensitivities for both UA and FA (0.53 and 0.494 μAμM−1.cm−2, respectively), and (iv) detection limits of 11.5 nM (UA) and 6.20 nM (FA). The electrode exhibited good repeatability (RSD = 4.4%), acceptable reproducibility (RSD = 4.1%), and excellent stability (91.8% over one-month storage). The method was applied to analyze spiked serum samples, and modified GCE is shown appreciable recoveries (97.1–98.8% and 96.8–98.0% for UA, and FA, respectively). [Figure not available: see fulltext.].

AB - In this study, a solution-processing based galvanic deposition approach is described for in-situ deposition of gold nanoparticles (AuNP) on delaminated titanium Ti3C2Tx nanosheets under ultrasonication. The nanocomposite (AuNP@Ti3C2Tx) was placed on a glassy carbon electrode (GCE) and then applied to electrochemically with label-free, and simultaneously sense uric acid (UA), and folic acid (FA) at physiological pH. The modified GCE has attractive figures of merit: (i) The working potentials for UA and AA are well separated (+0.35 V and 0.70 V vs. Ag|AgCl); (ii) wide linear responses (from 0.03–1520 μM for UA and from 0.02–3580 μM for FA; (iii) good electrochemical sensitivities for both UA and FA (0.53 and 0.494 μAμM−1.cm−2, respectively), and (iv) detection limits of 11.5 nM (UA) and 6.20 nM (FA). The electrode exhibited good repeatability (RSD = 4.4%), acceptable reproducibility (RSD = 4.1%), and excellent stability (91.8% over one-month storage). The method was applied to analyze spiked serum samples, and modified GCE is shown appreciable recoveries (97.1–98.8% and 96.8–98.0% for UA, and FA, respectively). [Figure not available: see fulltext.].

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