A high-performance oxygen evolution catalyst in neutral-pH for sunlight-driven CO2 reduction

Li Qin Zhou, Chen Ling, Hui Zhou, Xiang Wang, Joseph Liao, Gunugunuri K. Reddy, Liangzi Deng, Torin C. Peck, Ruigang Zhang, M. Stanley Whittingham, Chongmin Wang, Ching Wu Chu, Yan Yao, Hongfei Jia

研究成果: Article同行評審

55 引文 斯高帕斯(Scopus)


The efficiency of sunlight-driven reduction of carbon dioxide (CO2), a process mimicking the photosynthesis in nature that integrates the light harvester and electrolysis cell to convert CO2 into valuable chemicals, is greatly limited by the sluggish kinetics of oxygen evolution in pH-neutral conditions. Current non-noble metal oxide catalysts developed to drive oxygen evolution in alkaline solution have poor performance in neutral solutions. Here we report a highly active and stable oxygen evolution catalyst in neutral pH, Brownmillerite Sr2GaCoO5, with the specific activity about one order of magnitude higher than that of widely used iridium oxide catalyst. Using Sr2GaCoO5 to catalyze oxygen evolution, the integrated CO2 reduction achieves the average solar-to-CO efficiency of 13.9% with no appreciable performance degradation in 19 h of operation. Our results not only set a record for the efficiency in sunlight-driven CO2 reduction, but open new opportunities towards the realization of practical CO2 reduction systems.

期刊Nature communications
出版狀態Published - 2019 12月 1

All Science Journal Classification (ASJC) codes

  • 一般物理與天文學
  • 一般化學
  • 一般生物化學,遺傳學和分子生物學


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