A homolytic oxy-functionalization mechanism: intermolecular hydrocarbyl migration from M-R to vanadate oxo

Mu Jeng Cheng, Robert J. Nielsen, William A. Goddard

研究成果: Article同行評審

14 引文 斯高帕斯(Scopus)

摘要

A new mechanism for generating C-O bonds from metal-hydrocarbyls involving homolytic, intermolecular migration of the hydrocarbyl group to a vanadium oxo is reported. Responsible for the C-O bond in phenol formed by the reaction of OVCl3 with HgPh2, it may provide air-regenerable metal oxos a role in aerobic alkane oxidations.

原文English
頁(從 - 到)10994-10996
頁數3
期刊Chemical Communications
50
發行號75
DOIs
出版狀態Published - 2014 八月 21

All Science Journal Classification (ASJC) codes

  • 催化
  • 電子、光磁材料
  • 陶瓷和複合材料
  • 化學 (全部)
  • 表面、塗料和薄膜
  • 金屬和合金
  • 材料化學

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