A mesoporous metal-organic framework based on a shape-persistent macrocycle

Teng Hao Chen, Ilya Popov, Yu Chun Chuang, Yu Sheng Chen, Ognjen S. Miljanić

研究成果: Article同行評審

30 引文 斯高帕斯(Scopus)

摘要

A mesoporous Zn-based metal-organic framework (MOF) was prepared from a shape-persistent phenylene ethynylene macrocycle functionalized with three -COOH groups. The rigid ligand has a ∼9 Å wide central cavity which serves as a predesigned pore. The macrocycles [π⋯π] stack into pairs, with their carboxylate groups connected via three Zn3O14C6H2 clusters. The resulting MOF has a void volume of 86%.

原文English
頁(從 - 到)6340-6342
頁數3
期刊Chemical Communications
51
發行號29
DOIs
出版狀態Published - 2015 4月 14

All Science Journal Classification (ASJC) codes

  • 催化
  • 電子、光磁材料
  • 陶瓷和複合材料
  • 化學 (全部)
  • 表面、塗料和薄膜
  • 金屬和合金
  • 材料化學

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