A mesoporous metal-organic framework based on a shape-persistent macrocycle

Teng Hao Chen; Ilya Popov; Yu Chun Chuang; Yu Sheng Chen; Ognjen S. Miljanić

doi:10.1039/c5cc01635e

A mesoporous metal-organic framework based on a shape-persistent macrocycle

Teng Hao Chen, Ilya Popov, Yu Chun Chuang, Yu Sheng Chen, Ognjen S. Miljanić

藥學系

研究成果: Article › 同行評審

30 引文斯高帕斯（Scopus）

摘要

A mesoporous Zn-based metal-organic framework (MOF) was prepared from a shape-persistent phenylene ethynylene macrocycle functionalized with three -COOH groups. The rigid ligand has a ∼9 Å wide central cavity which serves as a predesigned pore. The macrocycles [π⋯π] stack into pairs, with their carboxylate groups connected via three Zn₃O₁₄C₆H₂ clusters. The resulting MOF has a void volume of 86%.

原文	English
頁（從 - 到）	6340-6342
頁數	3
期刊	Chemical Communications
卷	51
發行號	29
DOIs	https://doi.org/10.1039/c5cc01635e
出版狀態	Published - 2015 4月 14

All Science Journal Classification (ASJC) codes

催化
電子、光磁材料
陶瓷和複合材料
化學 (全部)
表面、塗料和薄膜
金屬和合金
材料化學

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10.1039/c5cc01635e

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AU - Chen, Yu Sheng

AU - Miljanić, Ognjen S.

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A mesoporous metal-organic framework based on a shape-persistent macrocycle

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