A New High Entropy Glycerate for High Performance Oxygen Evolution Reaction

Thi Xuyen Nguyen, Yen Hsun Su, Chia Chun Lin, Jrjeng Ruan, Jyh Ming Ting

研究成果: Article同行評審

24 引文 斯高帕斯(Scopus)

摘要

Herein, a new high entropy material is reported, i.e., a noble metal-free high entropy glycerate (HEG), synthesized via a simple solvothermal process. The HEG consists of 5 different metals of Fe, Ni, Co, Cr, and Mn. The unique glycerate structure exhibits an excellent oxygen evolution reaction (OER) activity with a low overpotential of 229 and 278 mV at current densities of 10 and 100 mA cm−2, respectively, in 1 m KOH electrolyte, outperforming its subsystems of binary-, ternary-, and quaternary-metal glycerates. The HEG also shows outstanding stability and durability in the alkaline electrolyte. The result demonstrates the significance of synergistic effect that gives additional freedoms to modify the electronic structure and coordination environment. Moreover, HEG@HEG electrolyzer shows a good overall water splitting performance and durability, requiring a cell voltage of 1.63 V to achieve a current density of 10 mA cm−2.

原文English
文章編號2002446
期刊Advanced Science
8
發行號6
DOIs
出版狀態Published - 2021 3月 17

All Science Journal Classification (ASJC) codes

  • 醫藥(雜項)
  • 化學工程 (全部)
  • 材料科學(全部)
  • 生物化學、遺傳與分子生物學(雜項)
  • 工程 (全部)
  • 物理與天文學 (全部)

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