A three-dimensional self-assembled SnS2-nano-dots@graphene hybrid aerogel as an efficient polysulfide reservoir for high-performance lithium-sulfur batteries

Liu Luo, Sheng Heng Chung, Arumugam Manthiram

研究成果: Article同行評審

55 引文 斯高帕斯(Scopus)

摘要

Reliable sulfur cathodes hold the key to realizing high-performance lithium-sulfur (Li-S) batteries, yet the electrochemical inefficiency and instability arising from the poor conductivity of sulfur and lithium sulfide together with polysulfide diffusion present challenges. We present here a new three-dimensional graphene aerogel embedded with in situ grown SnS2 nano-dots (SnS2-ND@G) as an efficient sulfur host. First, benefiting from a highly conductive, hierarchically porous, and mechanically self-supported architecture, the SnS2-ND@G aerogel enables the cathode to hold high sulfur content (75 wt%) and loading (up to 10 mg cm-2). Both values exceed most of the reported metal-compound-related cathode work (<60 wt% sulfur content and <3 mg cm-2 sulfur loading) in the literature. Second, this work takes advantage of a facile one-pot self-assembly fabrication, effectively guaranteeing a homogeneous deposition of SnS2 nano-dots in the graphene aerogel with a small amount of SnS2 (16 wt%). It greatly overcomes the shortcomings of physical incorporation methods to make metal-compound/carbon substrates reported in previous studies. More importantly, by rationally combining the physical entrapment from graphene and chemical adsorptivity from SnS2 nano-dots towards polysulfides, the SnS2-ND@G aerogel demonstrates remarkably improved polysulfide-trapping capability and electrochemical stability. As a result, a high peak capacity of 1234 mA h g-1, a high reversible capacity of 1016 mA h g-1 after 300 cycles, exceptional rate capability (C/10-3C rates), and impressive areal capacity (up to 11 mA h cm-2) are achieved. This work provides a viable path to integrate a conductive graphene network and nano-sized SnS2 as a promising cathode substrate for developing advanced Li-S batteries.

原文English
頁(從 - 到)7659-7667
頁數9
期刊Journal of Materials Chemistry A
6
發行號17
DOIs
出版狀態Published - 2018 一月 1

All Science Journal Classification (ASJC) codes

  • 化學 (全部)
  • 可再生能源、永續發展與環境
  • 材料科學(全部)

指紋

深入研究「A three-dimensional self-assembled SnS<sub>2</sub>-nano-dots@graphene hybrid aerogel as an efficient polysulfide reservoir for high-performance lithium-sulfur batteries」主題。共同形成了獨特的指紋。

引用此