Activation of dichloromethane by a V(III) thiolate complex: An example of S-based nucleophilic reactivity in an early transition metal thiolate

Tzu Tso Chen, Yu Sen Chen, Ya Ho Chang, Jung Ching Wang, Yi Fang Tsai, Gene Hsiang Lee, Tin Shen Kuo, Hua Fen Hsu

研究成果: Article同行評審

10 引文 斯高帕斯(Scopus)

摘要

A VIII thiolate complex activated C-Cl bond in dichloromethane via S-based nucleophilic attack. The reaction products, a VIII-Cl species (major one) and a VIV binding to a CH2 containing ligand (minor one) were obtained. The work demonstrates sulfur donors in the early-transition metal thiolates having strong nucleophilic characteristics.

原文English
頁(從 - 到)1109-1111
頁數3
期刊Chemical Communications
49
發行號11
DOIs
出版狀態Published - 2013 一月 10

All Science Journal Classification (ASJC) codes

  • 催化
  • 電子、光磁材料
  • 陶瓷和複合材料
  • 化學 (全部)
  • 表面、塗料和薄膜
  • 金屬和合金
  • 材料化學

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