A VIII thiolate complex activated C-Cl bond in dichloromethane via S-based nucleophilic attack. The reaction products, a VIII-Cl species (major one) and a VIV binding to a CH2 containing ligand (minor one) were obtained. The work demonstrates sulfur donors in the early-transition metal thiolates having strong nucleophilic characteristics.
|頁（從 - 到）||1109-1111|
|出版狀態||Published - 2013 1月 10|
All Science Journal Classification (ASJC) codes
- 化學 (全部)