An empirical formula to predict the overall irreversibility of counter-flow premixed flames of methane and its mixtures

Chien Ru Yu, Chih Yung Wu

研究成果: Article同行評審

7 引文 斯高帕斯(Scopus)

摘要

A novel method for estimating the non-equilibrium entropy generated in a premixed stretched methane flame is proposed. Counter-flow premixed methane flames were numerically investigated. The flame structure in terms of species, species production rate, and temperature was modeled using the San Diego mechanism with multicomponent diffusion. The local entropy generation of flames due to heat conduction, mass diffusion, viscous dissipation, and chemical reaction and the total irreversibility induced were analyzed for flames with various equivalence ratios at various temperatures, pressures, and counter-flow strain rates. The strain rate had a weak effect on the mass diffusion irreversibility and thermal conduction irreversibility but a strong effect on the chemical irreversibility. The overall irreversibility was highest at the equivalence ratio of 1.1. The heat conduction irreversibility, mass diffusion irreversibility, and chemical irreversibility all increased as the pressure was increased, and the chemical irreversibility increased as the temperature was increased. In all studied cases, the flame thickness decreased as the pressure or temperature was increased, and the flame thickness was inversely related to the non-equilibrium irreversibility. An empirical formula for predicting the irreversibility as a function of flame thickness was derived. The formula is valid not only for pure methane premixed flames but also for binary or triply blended fuel mixtures of methane, carbon monoxide, and hydrogen.

原文English
頁(從 - 到)14587-14599
頁數13
期刊Journal of Thermal Analysis and Calorimetry
147
發行號24
DOIs
出版狀態Published - 2022 12月

All Science Journal Classification (ASJC) codes

  • 凝聚態物理學
  • 物理與理論化學

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